7-甲氧基-3,7-二甲基辛醛合成路线 （共 20 条）
反应条件
pyridinium chlorochromate in dichloromethane T=20°C; 2 h;
参考文献
Ishmuratov; Yakovleva; Galyautdinova; Faifer; Kharisov; Zorin; Tolstikov
Chemistry of Natural Compounds, 2001 , vol. 37, # 5 p. 486 - 489
反应条件
sodium in benzene 1 h; Heating;
参考文献
Gupta, Anurag Ateet; Rastogi, Anita; Gupta, M. M.; Srivastava, Neera; Sengupta, A. K.; Athar, Mohd
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1983 , vol. 22, # 9 p. 948 - 951
反应条件
hydrogen; palladium on activated charcoal in methanol 1 h; Yield given;
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 110, # 11 p. 459 - 469
反应条件
1: 1) BuLi / 1) THF, -30 to 0 deg C, 10 min, 2) THF, r.t., 30 min 2: 1) Dibal, 2) H2O, silica gel / 1) petroleum ether, -78 to 0 deg C, 30 min, 2) 0 deg C, 1 h 3: H2 / 10percent Pd-C / methanol / 1 h View Scheme
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 110, # 11 p. 459 - 469
反应条件
1: 1) Dibal, 2) H2O, silica gel / 1) petroleum ether, -78 to 0 deg C, 30 min, 2) 0 deg C, 1 h 2: H2 / 10percent Pd-C / methanol / 1 h View Scheme
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 110, # 11 p. 459 - 469
反应条件
acetic acid; zinc; cob(I)alamin Ambient temperature;
参考文献
Helvetica Chimica Acta, , vol. 61, # 7 p. 2560 - 2578
反应条件
1.1: n-BuLi / tetrahydrofuran; hexane / 1 h / 20 °C 1.2: 85 percent / tetrahydrofuran; hexane / 0 - 20 °C 2.1: Hg(OAc)2 / 25 h / 5 - 20 °C 2.2: 97 percent / NaOH; NaBH4 / H2O / 3 h / 0 - 20 °C 3.1: 90 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / 20 °C View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 37, # 5 p. 486 - 489
反应条件
1.1: Hg(OAc)2 / 25 h / 5 - 20 °C 1.2: 97 percent / NaOH; NaBH4 / H2O / 3 h / 0 - 20 °C 2.1: 90 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / 20 °C View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 37, # 5 p. 486 - 489
反应条件
1.1: NaH / benzene; dimethylformamide / 3 h / 20 °C 1.2: 96 percent / benzene; dimethylformamide / 12 h / Heating 2.1: 81 percent / LiI / dimethylformamide / 12 h / Heating 3.1: n-BuLi / tetrahydrofuran; hexane / 1 h / 20 °C 3.2: 85 percent / tetrahydrofuran; hexane / 0 - 20 °C 4.1: Hg(OAc)2 / 25 h / 5 - 20 °C 4.2: 97 percent / NaOH; NaBH4 / H2O / 3 h / 0 - 20 °C 5.1: 90 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / 20 °C View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 37, # 5 p. 486 - 489
反应条件
1.1: 81 percent / LiI / dimethylformamide / 12 h / Heating 2.1: n-BuLi / tetrahydrofuran; hexane / 1 h / 20 °C 2.2: 85 percent / tetrahydrofuran; hexane / 0 - 20 °C 3.1: Hg(OAc)2 / 25 h / 5 - 20 °C 3.2: 97 percent / NaOH; NaBH4 / H2O / 3 h / 0 - 20 °C 4.1: 90 percent / pyridinium chlorochromate / CH2Cl2 / 2 h / 20 °C View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 37, # 5 p. 486 - 489
