雌甾-1,3,5(10)-三烯2,3,17-三醇合成路线 （共 26 条）
反应条件
acetyl chloride in methanol T=60°C; 1 h;
参考文献
Steroids, , vol. 68, # 4 p. 373 - 375
反应条件
diisobutylaluminium hydride in methanol; ethanol; toluene
反应条件
1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione in methanol; chloroform T=-25°C; 24 h;
参考文献
Tetrahedron Letters, , vol. 46, # 20 p. 3541 - 3544
反应条件
boron tribromide in dichloromethane 48 h; Ambient temperature;
参考文献
Australian Journal of Chemistry, , vol. 42, # 3 p. 421 - 432
反应条件
pyridine hydrochloride T=200 - 220°C;
参考文献
Journal of Organic Chemistry, , vol. 25, p. 585 - 588
反应条件
bioconversion by mushroom tyrosinase after complexation with β-cyclodextrin; Yield given;
参考文献
Phytochemistry (Elsevier), , vol. 29, # 5 p. 1551 - 1554
参考文献
Chemistry and Industry (London, United Kingdom), , p. 1454
Tetrahedron, , vol. 10, p. 144,146
反应条件
1.1: nBuLi; 1,1-dimethylpropoxide; diisopropylamine / tetrahydrofuran; hexane / 3 h / -78 °C 1.2: trimethylborate / tetrahydrofuran; hexane / 2 h / pH 6 / cooling 1.3: 99 percent / aq. H2O2 / tetrahydrofuran; hexane / 1 h / 20 °C 2.1: 58 percent / AcCl / methanol / 1 h / 60 °C View Scheme
参考文献
Steroids, , vol. 68, # 4 p. 373 - 375
反应条件
1: 75 percent / K2CO3 / dimethylformamide / 3.5 h / 90 - 95 °C 2: 1.) NaH, 2.) CuCl2 / 1.) DMF, RT, 10 min, 2.) DMF, 90-95 deg C, 30 min 3: 55 percent / boron tribromide / CH2Cl2 / 48 h / Ambient temperature View Scheme
参考文献
Australian Journal of Chemistry, , vol. 42, # 3 p. 421 - 432
反应条件
1: 1.) NaH, 2.) CuCl2 / 1.) DMF, RT, 10 min, 2.) DMF, 90-95 deg C, 30 min 2: 55 percent / boron tribromide / CH2Cl2 / 48 h / Ambient temperature View Scheme
参考文献
Australian Journal of Chemistry, , vol. 42, # 3 p. 421 - 432
