2-[2-[2-(2-苯氧乙氧基]乙氧基]乙氧基]乙醇合成路线 （共 16 条）
反应条件
hydrogenchloride; hydrogen; palladium on activated charcoal in ethanol P=3102.9 Torr; 12 h;
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
反应条件
potassium hydroxide in water 1.) 115 deg C, 1h; 2.) 120 deg C, 1h;
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
1: 52 percent / potassium tert-butoxide / tetrahydrofuran / 13 h / Heating 2: 89 percent / pyridine / CH2Cl2 / 13 h / Ambient temperature 3: 81 percent / toluene / 12 h / Heating 4: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr View Scheme
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
反应条件
1: 81 percent / toluene / 12 h / Heating 2: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr View Scheme
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
反应条件
1: 89 percent / pyridine / CH2Cl2 / 13 h / Ambient temperature 2: 81 percent / toluene / 12 h / Heating 3: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr View Scheme
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
反应条件
1: 81 percent / toluene / 12 h / Heating 2: 87 percent / H2, conc. HCl / 10percent Pd/C / ethanol / 12 h / 3102.9 Torr View Scheme
参考文献
Beadle, James R.; Korzeniowsky, Stephen H.; Rosenberg, David E.; Garcia-Slanga, Blanche J.; Gokel, George W.
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1594 - 1603
反应条件
1: 62 percent / phosphorous tribromide / pyridine / 0 - 50 °C 2: 67 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h 3: 48 percent / phosphorous tribromide / pyridine / 0 - 50 °C 4: 72 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h View Scheme
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
1: 48 percent / phosphorous tribromide / pyridine / 0 - 50 °C 2: 72 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h View Scheme
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
1: 67 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h 2: 48 percent / phosphorous tribromide / pyridine / 0 - 50 °C 3: 72 percent / 1.) potassium hydroxide / H2O / 1.) 115 deg C, 1h; 2.) 120 deg C, 1h View Scheme
参考文献
Jursic, Branko
Tetrahedron, 1988 , vol. 44, # 5 p. 1553 - 1558
反应条件
trifluoroacetic acid T=160°C; 5.00333 - 5.01167 h; Product distribution / selectivity;
参考文献
DOW GLOBAL TECHNOLOGIES INC.
Patent: WO2009/76275 A1, 2009 ;
Location in patent: Page/Page column 13-15 ;
