4-异硫氰酰基-2,2,6,6-四甲基哌啶1-氧基自由基合成路线 （共 8 条）
反应条件
triethylamine in benzene T=20°C;
参考文献
Zakrzewski, Jerzy; Hupko, Jarosllaw; Kryczka, Krzysztof
Monatshefte fur Chemie, 2003 , vol. 134, # 6 p. 843 - 850
反应条件
1: N-(2,2,6,6-tetramethylpiperidin-4-yl)acetamide With dihydrogen peroxide; tungstate anion T=20°C; 144 h; 2: With water; potassium hydroxide 30 h; Reflux; 3: thiophosgene With triethylamine in benzene T=10 - 17°C;
参考文献
Bioorganic and Medicinal Chemistry Letters, , vol. 21, # 1 p. 514 - 516
反应条件
triphenylphosphine 1 h; Heating;
参考文献
Hankovszky, H. O.; Hideg, K.; Lex, L.
Synthesis, 1981 , # 2 p. 147 - 149
反应条件
1.1: 197 g / diethyl ether / 3.5 h / 5 - 10 °C 2.1: K2CO3 / H2O / 0.25 h / 25 °C 2.2: 150.8 g / H2O2; sodium tungstate; disodium EDTA / H2O / 73 h 3.1: 49 percent / KOH / H2O / 29 h / Heating 4.1: 67 percent / Et3N / benzene / 20 °C View Scheme
参考文献
Monatshefte fur Chemie, , vol. 134, # 6 p. 843 - 850
反应条件
1: 49 percent / KOH / H2O / 29 h / Heating 2: 67 percent / Et3N / benzene / 20 °C View Scheme
参考文献
Monatshefte fur Chemie, , vol. 134, # 6 p. 843 - 850
反应条件
1: 86 percent / diethyl ether / Heating 2: 61 percent / PPh3 / 1 h / Heating View Scheme
参考文献
Synthesis, , # 2 p. 147 - 149
反应条件
1.1: K2CO3 / H2O / 0.25 h / 25 °C 1.2: 150.8 g / H2O2; sodium tungstate; disodium EDTA / H2O / 73 h 2.1: 49 percent / KOH / H2O / 29 h / Heating 3.1: 67 percent / Et3N / benzene / 20 °C View Scheme
参考文献
Monatshefte fur Chemie, , vol. 134, # 6 p. 843 - 850
反应条件
1: H2O2 2: KOH 3: 65 percent / 5 percent NaOH / 0.17 h View Scheme
参考文献
Carbohydrate research, , vol. 89, # 2 p. 211 - 220
