2-硝基重氮苯四氟硼酸盐合成路线 （共 41 条）
反应条件
iron(II) chloride in tetrachloromethane T=60°C; 3 h;
参考文献
Ding, Yiyuan; Song, Qingbao; Cheng, Kai; Qi, Chenze
Tetrahedron Letters, 2012 , vol. 53, # 46 p. 6269 - 6272,4
反应条件
palladium diacetate in methanol T=20°C;
参考文献
Advanced Synthesis and Catalysis, , vol. 350, # 10 p. 1577 - 1586
反应条件
1: With boron trifluoride diethyl etherate in dichloromethane
T=-15°C; 0.25 h;
2: With tert.-butylnitrite in dichloromethane
T=-15 - 0°C; 1 h;
参考文献
Casar, Zdenko; Leban, Ivan; Marechal, Alenka Majcen-Le; Lorcy, Dominique
Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 13 p. 1568 - 1573
反应条件
sodium nitrite in water
T=-5 - 0°C; 0.666667 h;
参考文献
Prasad Hari, Durga; Hering, Thea; Koenig, Burkhard
Angewandte Chemie - International Edition, 2014 , vol. 53, # 3 p. 725 - 728
Angew. Chem., 2013 , vol. 126, # 3 p. 743 - 747,5
反应条件
1: water / 0.17 h / 0 °C / |Inert atmosphere
2: sodium / ethanol / 2.17 h / 20 °C / |Inert atmosphere
3: sulfuryl dichloride / N,N-dimethyl-formamide / 4 h / 20 °C / |Reflux; |Inert atmosphere
View Scheme
参考文献
Wang, Rui; Chen, Lingxin; Liu, Ping; Wang, Yunqing; Zhang, Qin
Chemistry--A European Journal, 2012 , vol. 18, # 36 p. 11343 - 11349,7
反应条件
potassium fluoride in dichloromethane
参考文献
Baum,K.
Journal of Organic Chemistry, 1968 , vol. 33, p. 4333 - 4335
反应条件
palladium diacetate in 1,4-dioxane
T=20°C; Suzuki-Miyamura cross-coupling; chemoselective reaction;
参考文献
Kuethe, Jeffrey T.; Childers, Karla G.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 10 p. 1577 - 1586
反应条件
palladium diacetate in 1,4-dioxane
T=20°C; Suzuki-Miyamura cross-coupling; chemoselective reaction;
参考文献
Kuethe, Jeffrey T.; Childers, Karla G.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 10 p. 1577 - 1586
反应条件
2,6-di-tert-butyl-4-methylpyridine; gold(I) chloride; palladium dichloride; SIDip*HCl in acetonitrile
T=20°C; 24 h;
参考文献
Panda, Biswajit; Sarkar, Tarun K.
Chemical Communications, 2010 , vol. 46, # 18 p. 3131 - 3133
反应条件
1: water; palladium diacetate / 20 °C / Inert atmosphere
2: 2,6-dimethylpyridine; trifluoroacetic anhydride / toluene / -50 °C / Inert atmosphere; Reflux
3: 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 4 h / 150 °C / Sealed tube
4: sodium hydroxide / methanol / 0.5 h / 20 °C
5: palladium 10 on activated carbon; hydrogen / methanol / 2.17 h / 760.05 Torr
View Scheme
参考文献
Schwalm, Cristiane Storck; Correia, Carlos Roque D.
Tetrahedron Letters, 2012 , vol. 53, # 36 p. 4836 - 4840
