2-硝基重氮苯四氟硼酸盐合成路线 （共 41 条）
反应条件
potassium acetate; 18-crown-6 ether in chloroform
4 h; Ambient temperature;
参考文献
Luxen, Andre; Christiaens, Leon
Tetrahedron Letters, 1982 , vol. 23, # 38 p. 3905 - 3908
反应条件
copper acetylacetonate; copper
T=40°C; 0.5 h;
参考文献
Citterio, Attilio; Ferrario, Francesco
Journal of Chemical Research, Miniprint, 1983 , # 12 p. 2656 - 2668
反应条件
1.1: water; palladium diacetate / 20 °C / Inert atmosphere
2.1: 2,6-dimethylpyridine; trifluoroacetic anhydride / toluene / -50 °C / Inert atmosphere; Reflux
3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 4 h / 150 °C / Sealed tube
4.1: sodium hydroxide / methanol / 0.5 h / 20 °C
5.1: palladium 10 on activated carbon; hydrogen / methanol / 2.17 h / 760.05 Torr
6.1: magnesium sulfate; trifluoroacetic acid / dichloromethane / 3 h / 60 °C / Sealed tube
6.2: pH 9
View Scheme
参考文献
Schwalm, Cristiane Storck; Correia, Carlos Roque D.
Tetrahedron Letters, 2012 , vol. 53, # 36 p. 4836 - 4840
反应条件
1.1: water; palladium diacetate / 20 °C / Inert atmosphere
2.1: 2,6-dimethylpyridine; trifluoroacetic anhydride / toluene / -50 °C / Inert atmosphere; Reflux
3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / toluene / 4 h / 150 °C / Sealed tube
4.1: sodium hydroxide / methanol / 0.5 h / 20 °C
5.1: palladium 10 on activated carbon; hydrogen / methanol / 2.17 h / 760.05 Torr
6.1: magnesium sulfate; trifluoroacetic acid / dichloromethane / 18 h / 20 °C / Inert atmosphere
6.2: pH 9
View Scheme
参考文献
Schwalm, Cristiane Storck; Correia, Carlos Roque D.
Tetrahedron Letters, 2012 , vol. 53, # 36 p. 4836 - 4840
反应条件
1: CH2Cl2
2: 10 percent / t-BuOK, (tert-butoxycarbonyl)methyl isocyanide / dimethylsulfoxide / 1.) room temperature, 30 min, 2.) 5-10 deg C
View Scheme
参考文献
Dell'Erba, Carlo; Novi, Marino; Petrillo, Giovanni; Tavani, Cinzia
Tetrahedron, 1997 , vol. 53, # 6 p. 2125 - 2136
反应条件
in ethanol
T=25°C; Heck Reaction; 48 h;
参考文献
Li, Xing; Wang, Li-Chao; Chang, Hong-Hong; Zhang, Cong-Xia; Wei, Wen-Long
Applied Catalysis A: General, 2013 , vol. 462-463, p. 15 - 22
反应条件
1.1: H2O / 0.17 h / 0 °C
2.1: 24.20 g / Na / ethanol / 1 h / 20 °C
3.1: NaSH*H2O; aq. NaOH / 20 °C
3.2: 90 percent / aq. NaOH / 2 h / Heating
4.1: 66 percent / K2CO3 / ethanol / 0.5 h / Heating
View Scheme
参考文献
Casar, Zdenko; Leban, Ivan; Marechal, Alenka Majcen-Le; Lorcy, Dominique
Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 13 p. 1568 - 1573
反应条件
potassium acetate; 18-crown-6 ether in chloroform
4 h; Ambient temperature;
参考文献
Luxen, Andre; Christiaens, Leon
Tetrahedron Letters, 1982 , vol. 23, # 38 p. 3905 - 3908
反应条件
5-palladium/activated carbon in methanol
T=25°C; Suzuki-Miyaura reaction; 12 h;
参考文献
Felpin, Francois-Xavier; Fouquet, Eric; Zakri, Cecile
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 4 p. 649 - 655
反应条件
C33H25BF2I2N2 in dimethyl sulfoxide
T=20°C; 1 h; Inert atmosphereIrradiation; Catalytic behavior; Reagent/catalyst;
参考文献
Huang, Ling; Zhao, Jianzhang
RSC Advances, 2013 , vol. 3, # 45 p. 23377 - 23388
