4,4-二(2-乙基己基)-二噻吩并环戊二烯合成路线 （共 3 条）
反应条件
N-benzyl-N,N,N-trimethyl-ammonium chloride; zinc(II) chloride in N,N-dimethyl-formamide
T=20°C; 1.5 h; BrominationInert atmosphere;
参考文献
Lange, Alexander; Krueger, Hartmut; Ecker, Bernhard; Tunc, Ali Veysel; Von Hauff, Elizabeth; Morana, Mauro
Journal of Polymer Science, Part A: Polymer Chemistry, 2012 , vol. 50, # 8 p. 1622 - 1635
反应条件
1: With N-bromosuccinmide in N,N-dimethyl-formamide
T=0 - 20°C; Inert atmosphereDarkness;
2: With water in N,N-dimethyl-formamide
T=0°C; Inert atmosphere;
参考文献
Marin, Lidia; Van Mierloo, Sarah; Zhang, Yuexing; Robeyns, Koen; Champagne, Benoit; Adriaensens, Peter; Lutsen, Laurence; Vanderzande, Dirk; Maes, Wouter
Tetrahedron, 2013 , vol. 69, # 10 p. 2260 - 2267
反应条件
1: 4,4-bis(2-ethylhexyl)-4H-cyclopenta(2,1-b:3,4-b’)-dithiophene With n-butyllithium in tetrahydrofuran; hexanes
T=-78 - 20°C; 4 h;
2: trimethylstannyl chloride in tetrahydrofuran; hexanes
T=-78 - 20°C;
参考文献
Konarka Technologies, Inc.
Patent: US7772485 B2, 2010 ;
Location in patent: Page/Page column 12 ;
