N,N,N',N'-四甲基联苯胺合成路线 （共 97 条）
反应条件
tert.-butyl lithium; triethylamine; iron(II) chloride in tetrahydrofuran T=-78 - 25°C; 4 h; Inert atmosphere;
参考文献
Organic Letters, , vol. 15, # 18 p. 4690 - 4693
反应条件
oxygen; sodium acetate; palladium diacetate in water T=23°C; 10 h;
参考文献
Tetrahedron Letters, , vol. 43, # 44 p. 7899 - 7902
反应条件
iron(III) chloride; 1,2-dichloro-ethane in tetrahydrofuran T=20°C; 0.166667 h;
参考文献
Organic Letters, , vol. 7, # 10 p. 1943 - 1946
反应条件
copper diacetate; palladium diacetate in tetrahydrofuran; N,N-dimethyl acetamide T=80°C; 3 h; chemoselective reaction;
参考文献
Journal of Chemical Research, , vol. 37, # 11 p. 674 - 676
反应条件
FeCl3·6H2O in toluene T=85°C; 2 h; SolventReagent/catalystTemperatureConcentration;
参考文献
Journal of Organic Chemistry, , vol. 78, # 11 p. 5218 - 5226
反应条件
1: 1-bromocyclohexane With [Fe(C2H4)4][Li(tmeda)]2 in tetrahydrofuran T=-20°C; 2: 4-N,N-dimethylaminophenyl magnesium halide in tetrahydrofuran; diethyl ether T=-20°C; Further stages.;
参考文献
Journal of the American Chemical Society, , vol. 130, # 27 p. 8773 - 8787
反应条件
tetraethylammonium p-toluenesulfonate; tetrakis(triphenylphosphine) palladium(0) in N,N-dimethyl-formamide Ambient temperatureelectrolysis;
参考文献
Tetrahedron Letters, , vol. 26, # 13 p. 1655 - 1658
反应条件
P(pyrrolidinyl)3; [Ni(PEt3)4] in acetonitrile T=80°C; 20 h;
参考文献
Chemical Communications, , # 1 p. 47 - 48
反应条件
sodium hydroxide; [PdCl2(P(3,4-(18-crown-6)-phenyl)2(C6H5))2] T=140°C; 5 h;
参考文献
Organic Letters, , vol. 8, # 16 p. 3517 - 3520
反应条件
1: p-toluidine With n-butyllithium; ZnCl2*TMEDA in tetrahydrofuran; hexane T=0 - 20°C; 0.5 h; Inert atmosphereSchlenk technique; 2: [4-(N,N-dimethylamino)-phenyl]-magnesium bromide With N,N'-dimethyl-N,N'-propyleneurea; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane in tetrahydrofuran; hexane T=0 - 20°C; 3 h; Inert atmosphereSchlenk technique;
参考文献
Organic Letters, , vol. 14, # 21 p. 5570 - 5573,4
