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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
环十七酮
合成路线
(共 33 条)
3661-77-6
环十七酮
→
反应条件
502-72-7
环十五烷酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
830-13-7
环十二酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux 13.1: iodine; potassium hydroxide / -5 - 0 °C 14.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 15.1: methanol; water; sodium hydroxide / 5 h / Reflux 15.2: 1 h / Reflux View Scheme
参考文献
Helvetica Chimica Acta, , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
832-10-0
环三癸酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
878-13-7
环十一酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux 13.1: iodine; potassium hydroxide / -5 - 0 °C 14.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 15.1: methanol; water; sodium hydroxide / 5 h / Reflux 15.2: 1 h / Reflux 16.1: iodine; potassium hydroxide / -5 - 0 °C 17.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 18.1: methanol; water; sodium hydroxide / 5 h / Reflux 18.2: 1 h / Reflux View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
2424-90-0
十七烷二酸
反应条件
chromium(VI) oxide; acetic acid
参考文献
Ruzicka
Helvetica Chimica Acta, 1926 , vol. 9, p. 247
Full Text Show Details
Ruzicka; Stoll; Schinz
Helvetica Chimica Acta, 1926 , vol. 9, p. 250,260
Helvetica Chimica Acta, 1928 , vol. 11, p. 671 Anm. 3, 685
3661-77-6
环十七酮
→
反应条件
2550-52-9
环十二酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
33059-17-5
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux 13.1: iodine; potassium hydroxide / -5 - 0 °C 14.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 15.1: methanol; water; sodium hydroxide / 5 h / Reflux 15.2: 1 h / Reflux 16.1: potassium tert-butylate / tert-butyl alcohol / 50 °C View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
3603-99-4
环十四烷-1-酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
3661-77-6
环十七酮
→
反应条件
1502-06-3
环癸酮
反应条件
1.1: iodine; potassium hydroxide / -5 - 0 °C 2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 3.1: methanol; water; sodium hydroxide / 5 h / Reflux 3.2: 1 h / Reflux 4.1: iodine; potassium hydroxide / -5 - 0 °C 5.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 6.1: methanol; water; sodium hydroxide / 5 h / Reflux 6.2: 1 h / Reflux 7.1: iodine; potassium hydroxide / -5 - 0 °C 8.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 9.1: methanol; water; sodium hydroxide / 5 h / Reflux 9.2: 1 h / Reflux 10.1: iodine; potassium hydroxide / -5 - 0 °C 11.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 12.1: methanol; water; sodium hydroxide / 5 h / Reflux 12.2: 1 h / Reflux 13.1: iodine; potassium hydroxide / -5 - 0 °C 14.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 15.1: methanol; water; sodium hydroxide / 5 h / Reflux 15.2: 1 h / Reflux 16.1: iodine; potassium hydroxide / -5 - 0 °C 17.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 18.1: methanol; water; sodium hydroxide / 5 h / Reflux 18.2: 1 h / Reflux 19.1: iodine; potassium hydroxide / -5 - 0 °C 20.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 24 h / 20 °C 21.1: methanol; water; sodium hydroxide / 5 h / Reflux 21.2: 1 h / Reflux View Scheme
参考文献
Chapuis, Christian; Robvieux, Fabrice; Cantatore, Carole; Saint-Leger, Christine; Maggi, Laurent
Helvetica Chimica Acta, 2012 , vol. 95, # 3 p. 428 - 447
98221-89-7
→
反应条件
3661-77-6
环十七酮
反应条件
hydrogenchloride; zinc in 1,4-dioxane; water T=95 - 100°C; 17 h;
参考文献
Singh, Arpita; Singhal, Nishi; Agrawal, Hemlata; Yadav, Ashok K.
Indian Journal of Chemistry - Section B Organic and Medicinal Chemistry, 2002 , vol. 41, # 2 p. 423 - 426
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