2,4-二硝基-1-(4-硝基苯基)苯合成路线 (共 3 条)
反应条件
1: 1-iodo-2,4-dinitrobenzene With 2,4,6-trimethylphenylmagnesium bromide in tetrahydrofuran
T=-40°C; 0.0166667 h;
2: With zinc dibromide in tetrahydrofuran
T=-40°C; 0.166667 h;
3: para-nitro iodo-benzene With trifuran-2-yl-phosphane; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran
T=20°C; Negishi reaction; 4 h;
参考文献
Sapountzis, Ioannis; Dube, Henry; Lewis, Robert; Gommermann, Nina; Knochel, Paul
Journal of Organic Chemistry, 2005 , vol. 70, # 7 p. 2445 - 2454
反应条件
sulfuric acid
T=-5°C;
参考文献
Raudnitz
Chemische Berichte, 1927 , vol. 60, p. 742
Chemische Berichte, 1928 , vol. 61, p. 246
参考文献
Forrest,J.
Journal of the Chemical Society, 1960 , p. 594 - 601