2-甲基-2-苯基-1,3-二氧戊环合成路线 （共 91 条）
反应条件
toluene-4-sulfonic acid in ethanol Cyclization;
参考文献
Khalaj; Amanlou; Jorjani
Pharmacy and Pharmacology Communications, 1998 , vol. 4, # 4 p. 201 - 203
反应条件
titanium tetrachloride in dichloromethane T=0°C;
参考文献
Mastagli,P.; de Nanteuil,M.
Comptes Rendus des Seances de l'Academie des Sciences, Serie C: Sciences Chimiques, 1969 , vol. 268, p. 1970 - 1972
反应条件
1: With 9-bora-bicyclo[3.3.1]nonane in toluene 18 h; Inert atmosphereReflux; 2: With dihydrogen peroxide; sodium hydroxide in ethanol T=20°C; 2 h; Inert atmosphereReflux;
参考文献
Soderquist, John A.; Kock, Iveliz; Estrella, Maria E.
Organic Process Research and Development, 2006 , vol. 10, # 5 p. 1076 - 1079
反应条件
1: With sodium lauryl sulfate; toluene-4-sulfonic acid in hexane; water T=25°C; 2: in hexane T=25°C; 19 h; Further stages.;
参考文献
University of Iowa Research Foundation
Patent: US2009/299102 A1, 2009 ;
Location in patent: Page/Page column 6-7 ;
反应条件
lithium aluminium tetrahydride; zirconium tetrachloride in diethyl ether T=30°C; Reduction; 12 h;
参考文献
Shaozu, Wu; Tianhui, Ren; Ning, Chen; Yulan, Zhang
Organic Preparations and Procedures International, 1991 , vol. 23, # 4 p. 427 - 431
反应条件
1,3-bis-(diphenylphosphino)propane; [NEt3H]BF4; 1-n-butyl-3-methylimidazolium tetrafluoroborate; palladium diacetate; diisopropylamine
T=115°C; Heck arylation; 2 h;
参考文献
Mo, Jun; Xiao, Jianliang
Angewandte Chemie - International Edition, 2006 , vol. 45, # 25 p. 4152 - 4157
反应条件
indium trifluoromethanesulfonate in benzene
8 h; Heating;
参考文献
Gregg, Brian T.; Golden, Kathryn C.; Quinn, John F.
Tetrahedron, 2008 , vol. 64, # 15 p. 3287 - 3295
反应条件
potassium carbonate; Tedicyp; bis(η3-allyl-μ-chloropalladium(II)) in N,N-dimethyl-formamide
T=130°C; Heck reaction; 20 h;
参考文献
Kondolff, Isabelle; Doucet, Henri; Santelli, Maurice
Synlett, 2004 , # 9 p. 1561 - 1564
反应条件
palladium diacetate; 1,3-bis-(diphenylphosphino)propane; triethylamine in N,N-dimethyl-formamide
T=80°C; 24 h;
参考文献
Larhed, Mats; Hallberg, Anders
Journal of Organic Chemistry, 1997 , vol. 62, # 22 p. 7858 - 7862
反应条件
palladium diacetate; 1,3-bis-(diphenylphosphino)propane; thallous acetate; triethylamine in N,N-dimethyl-formamide
T=80°C; 144 h;
参考文献
Larhed, Mats; Hallberg, Anders
Journal of Organic Chemistry, 1997 , vol. 62, # 22 p. 7858 - 7862
