2-氧代-4-甲基戊酸甲酯合成路线 （共 14 条）
反应条件
tert.-butylnitrite; water; iodine; acetic acid in dichloromethane T=0 - 20°C; Inert atmosphereDarkness; ReactivityMechanism; Reagent/catalyst;
参考文献
Werardo, Giancarlo; Geatti, Paola; Gambi, Alberto
Journal of Physical Organic Chemistry, 2009 , vol. 22, # 1 p. 24 - 30
反应条件
1: POCl3 / toluene / 16 h / Heating 2: KI / acetone / 3 h / Heating 3: Zn, MeOH / 20 °C 4: H2 / (S,S)-bppm, (bicyclo<2.2.1>hepta-2,5-diene)chlororhodium(I) dimer / methanol / 2585.7 Torr / Ambient temperature View Scheme
参考文献
Scott, John W.; Keith, Dennis D.; Nix, George; Parrish, David R.; Remington, Stuart; et al.
Journal of Organic Chemistry, 1981 , vol. 46, p. 5086 - 5093
反应条件
1: POCl3 / toluene / 16 h / Heating
2: KI / acetone / 3 h / Heating
3: Zn, MeOH / 20 °C
View Scheme
参考文献
Scott, John W.; Keith, Dennis D.; Nix, George; Parrish, David R.; Remington, Stuart; et al.
Journal of Organic Chemistry, 1981 , vol. 46, p. 5086 - 5093
反应条件
1: POCl3
2: 1.) KI; 2.) NH3 / 1.) acetone; 2.) MeOH
View Scheme
参考文献
Shin, Chung-gi; Yonezawa, Yasuchika; Ohno, Hideki
Agricultural and Biological Chemistry, 1987 , vol. 51, # 7 p. 2033 - 2034
