[(2-溴苯基)甲基]三苯基-鏻溴化物合成路线 （共 15 条）
反应条件
sodium ethanolate in ethanol
1.) 30-50 deg C, 30 min, 2.) reflux, 1 h; Yields of byproduct given;
参考文献
Terfort, Andreas; Brunner, Henri
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 12 p. 1467 - 1479
反应条件
1: (2-bromo-benzyl)-triphenylphosphonium bromide With potassium tert-butylate in tetrahydrofuran
T=0°C;
2: ortho-bromobenzaldehyde in tetrahydrofuran
参考文献
Caruso Jr., Anthony; Siegler, Maxime A.; Tovar, John D.
Angewandte Chemie - International Edition, 2010 , vol. 49, # 25 p. 4213 - 4217
反应条件
2: TsNHNH2, NaOAc / ethanol / Heating
View Scheme
参考文献
Kelly; Li; Bhushan
Tetrahedron Letters, 1990 , vol. 31, # 2 p. 161 - 164
反应条件
1.1: EtONa / ethanol
1.2: ethanol / Heating
2.1: 43.3 g / I2 / heptane
3.1: 2.1 percent / (DHQD)2PHAL; AD-mix-β
View Scheme
参考文献
Wyatt, Paul; Hudson, Andrew; Charmant, Jonathan; Orpen, A. Guy; Phetmung, Hirihattaya
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 11 p. 2218 - 2232
反应条件
1: 23.0 g / sodium ethoxide / ethanol / Ambient temperature
2: 1.) Mg / 1.) THF, 2.) room temperature
View Scheme
参考文献
Munro, David P.; Sharp, John T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1984 , # 4 p. 849 - 858
