1-羟基-3-甲基丁烷-2-酮合成路线 (共 13 条)
反应条件
Pseudomonas putida ML 2; wild type strain in phosphate buffer
T=4°C; Oxidation; addition; pH=7.5; 24 h; Enzymatic reaction; Product distributionKinetics; Further Variations:Reagentsaddition of propylene glycol;
参考文献
Boyd, Derek R.; Clarke, David; Cleij, Marcel C.; Hamilton, John T.G.; Sheldrake, Gary N.
Monatshefte fur Chemie, 2000 , vol. 131, # 6 p. 673 - 685
反应条件
air; dihydrogen peroxide
Oxidation; 0.5 h; UV-irradiation; Product distributionKinetics; Further Variations:reaction time;
参考文献
Benkelberg; Boge; Seuwen; Warneck
Physical Chemistry Chemical Physics, 2000 , vol. 2, # 18 p. 4029 - 4039
反应条件
thallium(III) sulphate in sulfuric acid; water
ΔΔH(excit.), ΔΔS(excit.); oxidation; effect of temp. on the selectivity of the oxidation; dependence of selectivity on sulphuric acid conc.; Thermodynamic data;
参考文献
Pechal, Miroslav; Strasak, Milan
Journal fuer Praktische Chemie (Leipzig), 1984 , vol. 326, # 3 p. 374 - 380