5-甲基-1,2-苯并菲合成路线 （共 15 条）
反应条件
palladium on activated charcoal T=260°C;
参考文献
Levy, Louis A.; Sashikumar, V. P.
Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1760 - 1763
反应条件
palladium on activated charcoal T=300 - 320°C;
参考文献
Bachmann; Edgerton
Journal of the American Chemical Society, 1940 , vol. 62, p. 2550,2551
反应条件
1: 79 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / benzene / 1 h / Heating 2: 85 percent / 10percent Pd/C / 260 °C View Scheme
参考文献
Levy, Louis A.; Sashikumar, V. P.
Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1760 - 1763
反应条件
1: 88 percent / various solvent(s) / 8 h / 230 °C 2: 79 percent / 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) / benzene / 1 h / Heating 3: 85 percent / 10percent Pd/C / 260 °C View Scheme
参考文献
Levy, Louis A.; Sashikumar, V. P.
Journal of Organic Chemistry, 1985 , vol. 50, # 10 p. 1760 - 1763
反应条件
2: palladium coal / 300 - 320 °C View Scheme
参考文献
Bachmann; Edgerton
Journal of the American Chemical Society, 1940 , vol. 62, p. 2550,2551
反应条件
1: 80 percent / pyridinium chlorochromate / CH2Cl2 / 3 h / Ambient temperature 2: 1.) hydrazine, 2.) 40percent NaOH / 1.) diethylene glycol, 1 h, reflux, 2.) a) 0 deg C, b) 30 min, 50-60 deg C, c) 1 h, reflux View Scheme
参考文献
Amin, Shantu; Camanzo, Joseph; Huie, Keith; Hecht, Stephen S.
Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 381 - 384
反应条件
1: 62 percent / TiCl4 / CH2Cl2 / 1) -78 deg C, 2 h, 2) RT, 48 h 2: Pd/C View Scheme
参考文献
Raddo, Pasquale Di; Harvey, Ronald G.
Tetrahedron Letters, 1988 , vol. 29, # 32 p. 3885 - 3886
反应条件
sodium hydroxide; hydrazine 1.) diethylene glycol, 1 h, reflux, 2.) a) 0 deg C, b) 30 min, 50-60 deg C, c) 1 h, reflux; Yield given. Multistep reaction;
参考文献
Amin, Shantu; Camanzo, Joseph; Huie, Keith; Hecht, Stephen S.
Journal of Organic Chemistry, 1984 , vol. 49, # 2 p. 381 - 384
反应条件
iodine; oxygen Irradiation;
参考文献
Browne,C.E. et al.
Journal of Organic Chemistry, 1978 , vol. 43, # 9 p. 1656 - 1660
反应条件
iodine; oxygen Irradiation;
参考文献
Browne,C.E. et al.
Journal of Organic Chemistry, 1978 , vol. 43, # 9 p. 1656 - 1660
