1-硝基-3-(三氟甲基硫基)苯合成路线 （共 10 条）
反应条件
hydrogenchloride; tin(ll) chloride
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
反应条件
potassium phosphate; 1,10-phenanthroline; copper(I) isothiocyanate; sulfur; silver carbonate in N,N-dimethyl-formamide
T=130°C; 24 h; Inert atmosphereSealed tubeGlovebox;
参考文献
Zhai, Lijuan; Li, Yaming; Yin, Jun; Jin, Kun; Zhang, Rong; Fu, Xinmei; Duan, Chunying
Tetrahedron, 2013 , vol. 69, # 48 p. 10262 - 10266
反应条件
tert.-butylnitrite; boron trifluoride diethyl etherate in acetonitrile
T=50°C; Diazotization; Arylation; Trifluoromethylthiodediazoniation;
参考文献
Adams, Dave J.; Goddard, Andrew; Clark, James H.; Macquarrie, Duncan J.
Chemical Communications, 2000 , # 11 p. 987 - 988
反应条件
[2,2']bipyridinyl; [Cu(I)(CH3CN)4]PF6; potassium carbonate in diethylene glycol dimethyl ether
T=35°C; Schlenk techniqueInert atmosphere;
参考文献
Shao, Xinxin; Wang, Xueqiang; Yang, Tao; Lu, Long; Shen, Qilong
Angewandte Chemie - International Edition, 2013 , vol. 52, # 12 p. 3457 - 3460
Angew. Chem., 2013 , vol. 125, # 12 p. 3541 - 3544,4
反应条件
XeF2 in dichloromethane
T=-20 - 5°C;
参考文献
Sipyagin; Enshov; Kashtanov; Potemkin; Thrasher; Waterfeld
Russian Chemical Bulletin, 2004 , vol. 53, # 2 p. 420 - 434
反应条件
in acetonitrile
T=50°C; Arylation; Trifluoromethylthiodediazoniation;
参考文献
Adams, Dave J.; Goddard, Andrew; Clark, James H.; Macquarrie, Duncan J.
Chemical Communications, 2000 , # 11 p. 987 - 988
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
反应条件
ethanol; sulfuric acid; sodium nitrite
zuletzt unter Erwaermen;
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
反应条件
1: aqueous methanol. KOH-solution / anschliessendes Erwaermen mit Dimethylsulfat und wss. Natronlauge
2: chloroform; chlorine / Irradiation
3: antimony (III)-fluoride
View Scheme
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
反应条件
1: chloroform; chlorine / Irradiation
2: antimony (III)-fluoride
View Scheme
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
