1: 1-TMS-1-pentyne With diisobutylaluminium hydride in tetrahydrofuran; hexane
Inert atmosphereHeating;
2: 3-methylcyclopent-2-en-1-one With CuCl2·2H2O; C72H62Ag2N4O6S2 in tetrahydrofuran
T=22°C; 0.5 h; Inert atmosphereSealed vial; optical yield given as percent ee;
参考文献
May, Tricia L.; Dabrowski, Jennifer A.; Hoveyda, Amir H.
Journal of the American Chemical Society, 2011 , vol. 133, # 4 p. 736 - 739