3-甲氧基氧杂蒽-9-酮合成路线 （共 39 条）
反应条件
tert.-butylhydroperoxide; tetrabutylammomium bromide in water
T=120°C; 24 h; Schlenk techniqueSealed tube;
参考文献
Rao, Honghua; Ma, Xinyi; Liu, Qianzi; Li, Zhongfeng; Cao, Shengli; Li, Chao-Jun
Advanced Synthesis and Catalysis, 2013 , vol. 355, # 11-12 p. 2191 - 2196
反应条件
potassium phosphate; triphenylphosphine in toluene
T=110°C; 2 h; Schlenk techniqueInert atmosphereGreen chemistry; Catalytic behavior; Reagent/catalystSolventTemperature;
参考文献
Menendez, Cintia A.; Nador, Fabiana; Radivoy, Gabriel; Gerbino, Dario C.
Organic Letters, 2014 , vol. 16, # 11 p. 2846 - 2849
反应条件
1: 82.7 percent / copper-bronze, copper(I) iodide, K2CO3 / dimethylformamide / 4 h / 140 °C
2: 101 g / conc. H2SO4 / 1 h / 50 °C
View Scheme
参考文献
Passarotti; Valenti; Grianti; Marini
Bollettino Chimico Farmaceutico, 1994 , vol. 133, # 9 p. 592 - 596
反应条件
1: 82.7 percent / copper-bronze, copper(I) iodide, K2CO3 / dimethylformamide / 4 h / 140 °C
2: 101 g / conc. H2SO4 / 1 h / 50 °C
View Scheme
参考文献
Passarotti; Valenti; Grianti; Marini
Bollettino Chimico Farmaceutico, 1994 , vol. 133, # 9 p. 592 - 596
参考文献
Ungnade; Orwoll
Journal of the American Chemical Society, 1943 , vol. 65, p. 1736,1737
Organic Syntheses, 1955 , vol. Coll. Vol. III, p. 130
反应条件
1: 85 percent / PPA / 8 h / 90 °C
2: 90 percent / BeCl2 / toluene / 3 h / Heating
3: 65 percent / NaOH / methanol; H2O / Heating
View Scheme
参考文献
Sharghi, Hashem; Tamaddon, Fatemeh
Tetrahedron, 1996 , vol. 52, # 43 p. 13623 - 13640
反应条件
1: 90 percent / BeCl2 / toluene / 3 h / Heating
2: 65 percent / NaOH / methanol; H2O / Heating
View Scheme
参考文献
Sharghi, Hashem; Tamaddon, Fatemeh
Tetrahedron, 1996 , vol. 52, # 43 p. 13623 - 13640
反应条件
1: 85 percent / PPA / 8 h / 90 °C
2: 90 percent / BeCl2 / toluene / 3 h / Heating
3: 65 percent / NaOH / methanol; H2O / Heating
View Scheme
参考文献
Sharghi, Hashem; Tamaddon, Fatemeh
Tetrahedron, 1996 , vol. 52, # 43 p. 13623 - 13640
反应条件
1.1: AlCl3, aluminium chloride / diethyl ether / 8 h / 20 °C
1.2: Cooling with ice
2.1: pyridine; tetreamethyl ammonium hydroxide / water / 36 h / Reflux
View Scheme
参考文献
Cheng, Jen-Hao; Huang, A-Mei; Hour, Tzyh-Chyuan; Yang, Shyh-Chyun; Pu, Yeong-Shiau; Lin, Chun-Nan
European Journal of Medicinal Chemistry, 2011 , vol. 46, # 4 p. 1222 - 1231
参考文献
Fujikawa; Nakamura
Yakugaku Zasshi, 1944 , vol. 64, # 5 p. 274
Chem.Abstr., 1951 , p. 2906
