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乙二醇
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63148-62-9
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471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
372492-47-2
合成路线
(共 7 条)
372492-47-2
+
94-41-7
苯亚甲基苯乙酮
→
反应条件
1008-89-5
2-苯基吡啶
反应条件
silver hexafluoroantimonate; [{(η5-C5Me5)RhCl}2(μ-Cl)2]; acetic acid T=60°C; 3 h; Inert atmosphereDarkness;
参考文献
Yang, Lei; Qian, Bo; Huang, Hanmin
Chemistry - A European Journal, 2012 , vol. 18, # 31 p. 9511 - 9515
372492-47-2
→
反应条件
33421-36-2
2-(2-羟基苯基)吡啶
+
1452876-71-9
反应条件
2-hydroxy-1,3-isoindolinedione; oxygen; palladium dichloride in toluene T=100°C; P=760.051 Torr; 15 h; Schlenk technique; Kinetics; Overall yield = 68 percent; Overall yield = 140.2 mg;
参考文献
Yan, Yuepeng; Feng, Peng; Zheng, Qing-Zhong; Liang, Yu-Feng; Lu, Jing-Fen; Cui, Yuxin; Jiao, Ning
Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5827 - 5831
Angew. Chem., 2013 , vol. 125, # 22 p. 5939 - 5943,5
372492-47-2
→
反应条件
反应条件
1,1,2,2-tetrabromoethane; copper diacetate T=130°C; 5 h;
参考文献
Du, Zhi-Jun; Gao, Lian-Xun; Lin, Ying-Jie; Han, Fu-She
ChemCatChem, 2014 , vol. 6, # 1 p. 123 - 126
372492-47-2
+
823-96-1
三甲基环三硼氧烷
→
反应条件
反应条件
copper diacetate; air; p-benozquinone; palladium diacetate in dichloromethane T=100°C; 24 h; Product distribution; Further Variations:Reaction partnersReagentsSolventsreaction time;
参考文献
BRANDEIS UNIVERSITY MS134
Patent: WO2008/24953 A2, 2008 ;
Location in patent: Page/Page column 76 ;
372492-47-2
+
594-27-4
四甲基锡
→
反应条件
反应条件
1: ortho-deuterated 2-phenylpyridine With palladium diacetate in dichloromethane T=100°C; 2 h; 2: tetramethylstannane With p-benozquinone in dichloromethane 1 h; Heating / reflux; Product distribution / selectivity;
参考文献
BRANDEIS UNIVERSITY MS134
Patent: WO2008/24953 A2, 2008 ;
Location in patent: Page/Page column 77 ;
372492-47-2
+
13061-96-6
甲基硼酸
→
反应条件
反应条件
p-benozquinone; silver(l) oxide; palladium diacetate in 1,1-dimethylpropan-1-ol T=100°C; 6 h; Product distribution / selectivity;
参考文献
BRANDEIS UNIVERSITY MS134
Patent: WO2008/24953 A2, 2008 ;
Location in patent: Page/Page column 76-77 ;
372492-47-2
→
反应条件
4253-81-0
+
1345883-77-3
反应条件
oxygen; copper diacetate; silver nitrate in 1,2,3-trichloro propane T=130°C; 24 h; regioselective reaction;
参考文献
Zhang, Lin; Liu, Zhenhua; Li, Huiqin; Fang, Guichun; Barry, Badru-Deen; Belay, Tuemay Abadi; Bi, Xihe; Liu, Qun
Organic Letters, 2011 , vol. 13, # 24 p. 6536 - 6539