1,6-二碘代十二氟己烷合成路线 （共 26 条）
反应条件
1: iodine; Na2S2O8 / dimethylsulfoxide; H2O / 1 h / 20 °C 2: Na2S2O4 / dimethylsulfoxide / 100 °C 3: 54 percent / Na2S2O8; iodine / H2O; dimethylsulfoxide / 1 h / 20 °C View Scheme
参考文献
Journal of Fluorine Chemistry, , vol. 128, # 10 p. 1187 - 1190
参考文献
Journal of Fluorine Chemistry, , vol. 74, # 1 p. 59 - 68
反应条件
2: KI / 270 - 375 °C View Scheme
参考文献
Tetrahedron Letters, , p. 4761 - 4762
反应条件
iodine T=260°C; 10 h; other temp., time; Product distribution;
参考文献
J. Gen. Chem. USSR (Engl. Transl.), , vol. 60, # 3.2 p. 664 - 667,582 - 584
反应条件
cadmium in acetonitrile 1 h; Heatingother α,ω-diiodoperfluoroalkanes, var. solvent and temperature; Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 60, # 1 p. 1 - 12
反应条件
T=200°C; 24 h; other temperatures and times; Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 74, # 1 p. 59 - 68
反应条件
tetracarbonylnickel(0); acetonitrile 1.) 11 d, 2.) 130-150 deg C, 3 h; Yield given. Multistep reaction;
参考文献
Krespan, Carl G.; Dixon, David A.
Journal of Organic Chemistry, 1998 , vol. 63, # 1 p. 36 - 43
反应条件
1: 75 percent / CuI / acetonitrile / 15 h / 165 °C 2: 75 percent / KOH / ethanol / 5 h / 70 °C View Scheme
参考文献
Baum, Kurt; Bedford, Clifford D.; Hunadi, Ronald J.
Journal of Organic Chemistry, 1982 , vol. 47, # 12 p. 2251 - 2257
反应条件
dodecacarbonyltriiron T=100°C; P=7600 Torr; 12 h;
参考文献
Urata, Hisao; Kinoshita, Yoshihiro; Asanuma, Tatsuya; Kosukegawa, Osamu; Fuchikami, Takamasa
Journal of Organic Chemistry, 1991 , vol. 56, # 16 p. 4996 - 4999
→
63703-16-21,1,2,2,3,3,4,4,5,5,6,6-十二氟-1-碘己烷+
反应条件
sodium hydride 1.) DMF, 2.) DMF, 70 deg C, 10h, irradiation; Yield given. Multistep reaction;
参考文献
Chen, Qing-Yun; Chen, Mei-Jin
Journal of Fluorine Chemistry, 1991 , vol. 51, # 1 p. 21 - 32
