1-(4-硝基苯基)-1-丙酮合成路线 （共 24 条）
反应条件
diethyl ether; sodium hydride
anschl. mit Toluol-4-sulfonsaeure in Benzol;
参考文献
Puterbaugh et al.
Journal of the American Chemical Society, 1952 , vol. 74, p. 3438
反应条件
sodium dichromate; sulfuric acid; water
参考文献
Chaudhuri; Ghosh
Journal of the Indian Chemical Society, 1951 , vol. 28, p. 563
反应条件
oxygen; nitrogen(IV) oxide; ozone in dichloromethane
T=-10°C; 6 h; Yield given. Yields of byproduct given;
参考文献
Suzuki, Hitomi; Murashima, Takashi
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 7 p. 903 - 908
反应条件
lithium salt of 2-nitropropane in dimethyl sulfoxide
30 h;
参考文献
Norris,R.K.; Randles,D.
Australian Journal of Chemistry, 1976 , vol. 29, p. 2621 - 2629
反应条件
nitric acid
T=40 - 60°C;
参考文献
Comanducci; Pescitelli
Gazzetta Chimica Italiana, 1906 , vol. 36 II, p. 785
反应条件
hydrogenchloride in ethanol
参考文献
Zimmer,H.; Bercz,J.P.
Justus Liebigs Annalen der Chemie, 1965 , vol. 686, p. 107 - 114
反应条件
1: KOH / methanol; tetrahydrofuran
2: aq. HCl / ethanol
View Scheme
参考文献
Zimmer,H.; Bercz,J.P.
Justus Liebigs Annalen der Chemie, 1965 , vol. 686, p. 107 - 114
反应条件
1: (i) EtOH, (ii) /BRN= 2051909/
2: KOH / methanol; tetrahydrofuran
3: aq. HCl / ethanol
View Scheme
参考文献
Zimmer,H.; Bercz,J.P.
Justus Liebigs Annalen der Chemie, 1965 , vol. 686, p. 107 - 114
反应条件
sulfuric acid in acetonitrile
T=60°C; 0.5 h; Mechanism;
参考文献
Rafizadeh, Karim; Yates, Keith
Journal of Organic Chemistry, 1984 , vol. 49, # 9 p. 1500 - 1506
反应条件
sodium hydride; Spirolt;cyclohexan-1,3'-oxaziridingt;
1) DMF, 15 min 2) toluene, 15 min; Yield given. Multistep reaction;
参考文献
Wulf, Jens-Peter; Sienkiewicz, Krzysztof; Makosza, Mieczyslaw; Schmitz, Ernst
Liebigs Annalen der Chemie, 1991 , # 6 p. 537 - 538
