N,N-双-((S)-1-苯基乙基)二苯并[d,f][1,3,2]二氧杂膦-6-胺合成路线 （共 4 条）
反应条件
1: (S*,S*)-α,α'-dimethyldibenzylamine With n-butyllithium in tetrahydrofuran; hexane
T=-78 - -30°C; Inert atmosphere;
2: 2-chlorodibenzolt;d,fgt;-1,3,2-dioxaphosphepan in tetrahydrofuran; hexane
T=-78 - 20°C; Inert atmosphere;
参考文献
Smith, Craig R.; Rajanbabu
Organic Letters, 2008 , vol. 10, # 8 p. 1657 - 1659
反应条件
1: (S*,S*)-α,α'-dimethyldibenzylamine With triethylamine; phosphorus trichoride in tetrahydrofuran
T=20°C; 3 h;
2: 2,2'-dihydroxy-1,1'-biphenyl in tetrahydrofuran
T=20°C;
参考文献
Alexakis; Rosset; Allamand; March; Guillen; Benhaim
Synlett, 2001 , # 9 p. 1375 - 1378
Title/Abstract Full Text View citing articles Show Details
D'Augustin, Magali; Palais, Laeticia; Alexakis, Alexandre
Angewandte Chemie - International Edition, 2005 , vol. 44, # 9 p. 1376 - 1378
反应条件
triethylamine in tetrahydrofuran
参考文献
Bournaud, Chloee; Falciola, Caroline; Thomas-Lecourt; Rosset, Stephane; Alexakis, Alexandre; Micouin, Laurent
Organic Letters, 2006 , vol. 8, # 16 p. 3581 - 3584
反应条件
1: PCl3; triethylamine / toluene / 6 h / 70 °C
2: triethylamine / tetrahydrofuran; toluene / -78 - 20 °C
View Scheme
参考文献
Monti, Chiara; Gennari, Cesare; Piarulli, Umberto
Chemistry - A European Journal, 2007 , vol. 13, # 5 p. 1547 - 1558
