1,1,2,2,3,3,4,4-八氟丁烷合成路线 （共 19 条）
反应条件
hydrazine hydrate; zinc in N,N-dimethyl-formamide T=70°C; 2 h;
参考文献
Wu, Fang-Hong; Huang, Bing-Nan; Huang, Wei-Yuan
Journal of Fluorine Chemistry, 1995 , vol. 73, # 2 p. 159 - 160
反应条件
hydrazine hydrate; zinc in N,N-dimethyl-formamide T=70°C; 2 h;
参考文献
Wu, Fang-Hong; Huang, Bing-Nan; Huang, Wei-Yuan
Journal of Fluorine Chemistry, 1995 , vol. 73, # 2 p. 159 - 160
反应条件
ethylmagnesium bromide; magnesium in toluene 4 h; Heating / reflux; Product distribution / selectivity;
参考文献
Foosung Co., Ltd.
Patent: US7504547 B2, 2009 ;
Location in patent: Page/Page column 3 ;
反应条件
lead(II) bromide; aluminium 2 h; Ambient temperature;
参考文献
Hu, Chang-Ming; Tang, Xiao-Qing
Journal of Fluorine Chemistry, 1993 , vol. 61, # 3 p. 217 - 222
反应条件
methanol; carbon dioxide; tetra-n-butylammonium tetrafluoroborate T=50°C; P=71255.7 Torr; electrolysis: copper foil as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2000 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
tetra-n-butylammonium tetrafluoroborate T=50°C; P=71255.7 Torr; electrolysis: copper foil as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2000 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
tetra-n-butylammonium tetrafluoroborate T=50°C; P=71255.7 Torr; electrolysis: copper foil as cathode, platinum grid as anode, Ag quasi-reference electrode, -3.0 V, 2000 C; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Mazin; Mysov; Sterlin; Grinberg
Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35
反应条件
para-xylene; sodium acetate T=250°C;
参考文献
Malichenko,B.F. et al.
Journal of Organic Chemistry USSR (English Translation), 1975 , vol. 11, p. 2154 - 2157
Zhurnal Organicheskoi Khimii, 1975 , vol. 11, p. 2118 - 2122
反应条件
in diethyl ether 0.5 h;
参考文献
Saloutina; Zapevalov; Kodess; Saloutin
Russian Journal of Nondestructive Testing, 1997 , vol. 33, # 2 p. 265 - 272
参考文献
Brace,N.O.
Journal of Organic Chemistry, 1961 , vol. 26, p. 4005 - 4010
