2,4,6-三甲氧基苯甲酮合成路线 （共 31 条）
反应条件
silver trifluoromethanesulfonate in dichloromethane
T=20°C; Friedel-Crafts reaction; 1 h;
参考文献
Yamada, Takeshi; Mishima, Eri; Ueki, Kazuya; Yamago, Shigeru
Chemistry Letters, 2008 , vol. 37, # 6 p. 650 - 651
反应条件
1: N,N'-tetramethylethylenediamine, nBuLi / hexane
2: diethyl ether / -78 deg C to r.t.
View Scheme
参考文献
Nagel, Ulrich; Nedden, Hans Guenter
Chemische Berichte, 1997 , vol. 130, # 7 p. 989 - 1006
反应条件
1: TFA; Pd(OAc)2 / dimethylsulfoxide / 24 h / 100 °C
2: aq. TFA / dimethylsulfoxide / 2 h / 70 °C
View Scheme
参考文献
Zhou, Chengxiang; Larock, Richard C.
Journal of the American Chemical Society, 2004 , vol. 126, # 8 p. 2302 - 2303
反应条件
tetrafluoroboric acid; mercury(II) oxide in tetrahydrofuran
Ambient temperature; Yield given;
参考文献
Cadamuro, Silvano; Degani, Iacopo; Fochi, Rita; Gatti, Antonella; Regondi, Valeria
Synthesis, 1987 , # 3 p. 311 - 314
反应条件
1: 72 percent / pyridine / acetonitrile / 2 h / Ambient temperature
2: HgO, 35percent aq. tetrafluoroboric acid / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Cadamuro, Silvano; Degani, Iacopo; Fochi, Rita; Gatti, Antonella; Regondi, Valeria
Synthesis, 1987 , # 3 p. 311 - 314
反应条件
1: tetrafluoroboric acid/ether complex / acetonitrile
2: 72 percent / pyridine / acetonitrile / 2 h / Ambient temperature
3: HgO, 35percent aq. tetrafluoroboric acid / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Cadamuro, Silvano; Degani, Iacopo; Fochi, Rita; Gatti, Antonella; Regondi, Valeria
Synthesis, 1987 , # 3 p. 311 - 314
反应条件
1: tetrafluoroboric acid/ether complex / acetonitrile
2: 72 percent / pyridine / acetonitrile / 2 h / Ambient temperature
3: HgO, 35percent aq. tetrafluoroboric acid / tetrahydrofuran / Ambient temperature
View Scheme
参考文献
Cadamuro, Silvano; Degani, Iacopo; Fochi, Rita; Gatti, Antonella; Regondi, Valeria
Synthesis, 1987 , # 3 p. 311 - 314
反应条件
diethyl ether
T=12°C;
参考文献
Spaeth; Fuchs
Monatshefte fuer Chemie, 1921 , vol. 42, p. 272
反应条件
potassium hydroxide
T=100°C;
参考文献
Ciamician; Silber
Chemische Berichte, 1891 , vol. 24, p. 300
Chemische Berichte, 1892 , vol. 25, p. 1120
反应条件
trifluorormethanesulfonic acid
参考文献
El-Khagawa, Ahmed M.
Bulletin de la Societe Chimique de France, 1987 , # 2 p. 372 - 374
