双(甲硫代)(三甲基硅)甲烷合成路线 （共 7 条）
反应条件
1: methyl methylthiomethylsulfide With n-butyllithium in tetrahydrofuran; hexane T=-78 - 0°C; 4 h; 2: chloro-trimethyl-silane in tetrahydrofuran; hexane T=20°C; 15 h;
参考文献
Hagooly, Aviv; Rozen, Shlomo
Journal of Fluorine Chemistry, 2005 , vol. 126, # 8 p. 1239 - 1245
反应条件
(i) nBuLi, THF, hexane, (ii) /BRN= 1209228/; Multistep reaction;
参考文献
Seebach,D. et al.
Chemische Berichte, 1973 , vol. 106, p. 2277 - 2290
反应条件
1: (bis-methylsulfanyl-methyl)-trimethyl-silane With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; Inert atmosphere;
2: methyl 2-(2-bromoethyl)benzoate in tetrahydrofuran; hexane
T=-78 - 20°C; Inert atmosphere;
3: With tetrabutyl ammonium fluoride; water; 1,1,1,3,3,3-hexamethyl-disilazane in tetrahydrofuran
T=-78 - 20°C; Inert atmosphere;
参考文献
Genrich, Florian; Harms, Guido; Schaumann, Ernst; Gjikaj, Mimoza; Adiwidjaja, Gunadi
Tetrahedron, 2009 , vol. 65, # 28 p. 5577 - 5587
反应条件
1: (bis-methylsulfanyl-methyl)-trimethyl-silane With n-butyllithium in tetrahydrofuran; hexane
T=-78°C; Inert atmosphere;
2: methyl 2-(2-bromoethyl)benzoate in tetrahydrofuran; hexane
T=-78 - 20°C; Inert atmosphere;
参考文献
Genrich, Florian; Harms, Guido; Schaumann, Ernst; Gjikaj, Mimoza; Adiwidjaja, Gunadi
Tetrahedron, 2009 , vol. 65, # 28 p. 5577 - 5587
反应条件
1: (bis-methylsulfanyl-methyl)-trimethyl-silane With n-butyllithium in tetrahydrofuran; hexane
T=-78 - 0°C; 4 h;
2: Caprylic Aldehyde in tetrahydrofuran; hexane
T=20°C; 12 h;
参考文献
Hagooly, Aviv; Rozen, Shlomo
Journal of Fluorine Chemistry, 2005 , vol. 126, # 8 p. 1239 - 1245
反应条件
iodine in tetrahydrofuran
T=-78°C;
参考文献
Schlecker,R. et al.
Chemische Berichte, 1977 , vol. 110, p. 2880 - 2904
反应条件
lithium diisopropyl amide in tetrahydrofuran; N,N,N',N',N'',N''-hexamethylphosphoric triamide; hexane
参考文献
Buerstinghaus,R.; Seebach,D.
Chemische Berichte, 1977 , vol. 110, p. 841 - 851
