(2Z,6E)-3,7,11-三甲基十二碳-2,6,10-三烯-1-醇合成路线 （共 30 条）
反应条件
zeolite H-ZSM-5 in benzene 8 h; Heating;
参考文献
Reddy, P. Veera; Bhat, Sujata V.
Journal of the Indian Chemical Society, 1998 , vol. 75, # 10-12 p. 688 - 689
反应条件
1: 82 percent 2: NaI / acetone / 1 h / 0 - 2 °C 3: triethylamine / heptane / 5 h / 25 °C / Irradiation View Scheme
参考文献
Tetrahedron, , vol. 39, # 48 p. 2999 - 3004
反应条件
tributyl-amine; 2-fluoro-3-methyl-benzothiazolium fluorosulfate in dichloromethane
参考文献
Kobayashi,S. et al.
Chemistry Letters, 1977 , p. 1169 - 1172
反应条件
tributyl-amine; 2-fluoro-3-methyl-benzothiazolium fluorosulfate in dichloromethane
参考文献
Kobayashi,S. et al.
Chemistry Letters, 1977 , p. 1169 - 1172
反应条件
lithium aluminium tetrahydride in tetrahydrofuran
T=-78 - 25°C; 4 h; Inert atmosphere;
参考文献
Snyder, Scott A.; Treitler, Daniel S.; Brucks, Alexandria P.
Journal of the American Chemical Society, 2010 , vol. 132, # 40 p. 14303 - 14314
反应条件
lithium aluminium tetrahydride in benzene
T=55°C;
参考文献
Yu, Jose S.; Kleckley, Troy S.; Wiemer, David F.
Organic Letters, 2005 , vol. 7, # 22 p. 4803 - 4806
反应条件
1: in hexane
T=10 - 15°C; 21 h;
2: With water; sodium hydroxide in methanol
T=20 - 40°C; 2.25 h;
参考文献
Siewert, Jürgen; Wilkening, Burghard
Patent: US2013/289317 A1, 2013 ;
Location in patent: Paragraph 0118 - 0122; 0125 - 0137 ;
反应条件
1.1: NaH / tetrahydrofuran / 2 h / 0 °C
1.2: 73 percent / tetrahydrofuran / 3 h / 0 - 20 °C
2.1: diisobutyl aluminum hydride / toluene / 1 h / -78 °C
View Scheme
参考文献
Thulasiram, Hirekodathakallu V.; Poulter, C. Dale
Journal of the American Chemical Society, 2006 , vol. 128, # 49 p. 15819 - 15823
反应条件
1: 6,10-dimethyl-undeca-5,9-dien-2-one; Methyltriphenylphosphonium bromide With n-butyllithium in tetrahydrofuran
T=-78°C; 0.75 h;
2: With sec.-butyllithium in tetrahydrofuran
T=-78°C; 1 h;
3: formaldehyd in tetrahydrofuran
T=0 - 20°C;
参考文献
Yu, Jose S.; Kleckley, Troy S.; Wiemer, David F.
Organic Letters, 2005 , vol. 7, # 22 p. 4803 - 4806
反应条件
dibenzo-18-crown-6; sodium in tetrahydrofuran; ammonia
0.0333333 h;
参考文献
Zumbrunn, Albrecht; Uebelhart, Peter; Eugster, Conrad Hans
Helvetica Chimica Acta, 1985 , vol. 68, p. 1519 - 1539
