5,6,8,9-四氢-苯并环庚烯-7-酮合成路线 （共 22 条）
反应条件
1: acetic acid 2: tetrachloro-<1,4>benzoquinone; benzene View Scheme
参考文献
Muth et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1006,1008
反应条件
1: With sodium hydride; tert-butyl alcohol in toluene
Heating / reflux;
2: With acetic acid in water; toluene
T=20°C;
参考文献
Bristol-Myers Squibb Company
Patent: US2007/249583 A1, 2007 ;
Location in patent: Page/Page column 103-104 ;
US 20070249583 A1
反应条件
1: With sulfuric acid in water; acetonitrile
Inert atmosphere;
2: With sodium hydroxide in diethyl ether; water; acetonitrile
参考文献
UNIVERSITE DE HAUTE ALSACE; UNIVERSITE LOUIS PASTEUR
Patent: US2010/69504 A1, 2010 ;
Location in patent: Page/Page column 5 ;
US 20100069504 A1
反应条件
hydrogen; palladium on activated charcoal in ethyl acetate
P=1250.4 Torr; 18 h; Ambient temperature;
参考文献
Menard, D.; St-Jacques, M.
Tetrahedron, 1983 , vol. 39, # 7 p. 1041 - 1060
反应条件
hydrogen; potassium acetate; palladium on activated charcoal in ethanol
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
反应条件
hydrogen; potassium acetate; palladium on activated charcoal in ethanol
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
反应条件
1: (i) NaOMe, Et2O, (ii) H2O
2: H2, KOAc / Pd-C / ethanol
View Scheme
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
反应条件
1: aq. HCl / methanol
2: H2, KOAc / Pd-C / ethanol
View Scheme
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
反应条件
1: aq. NaOH, <PhCH2NMe3>Cl
2: Py / Heating
3: aq. HCl / methanol
4: H2, KOAc / Pd-C / ethanol
View Scheme
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
反应条件
1: Py / Heating
2: aq. HCl / methanol
3: H2, KOAc / Pd-C / ethanol
View Scheme
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
