5,6,8,9-四氢-苯并环庚烯-7-酮合成路线 （共 22 条）
反应条件
1: TsOH / ethanol
2: aq. NaOH, <PhCH2NMe3>Cl
3: Py / Heating
4: aq. HCl / methanol
5: H2, KOAc / Pd-C / ethanol
View Scheme
参考文献
Uyehara,T. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 273 - 274
参考文献
Muth et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1006,1008
反应条件
1: LiAlH4; diethyl ether
2: aqueous hydrobromic acid
4: phenyl lithium; N-methyl-aniline; diethyl ether
5: H2SO4
View Scheme
参考文献
Muth et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1006,1008
反应条件
1: aqueous hydrobromic acid
3: phenyl lithium; N-methyl-aniline; diethyl ether
4: H2SO4
View Scheme
参考文献
Muth et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1006,1008
反应条件
1: phenyl lithium; N-methyl-aniline; diethyl ether
2: H2SO4
View Scheme
参考文献
Muth et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1006,1008
反应条件
2: phenyl lithium; N-methyl-aniline; diethyl ether
3: H2SO4
View Scheme
参考文献
Muth et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 1006,1008
反应条件
T=200°C; P=0.1 Torr; durch Erhitzen des Thorium-Salzes;
参考文献
Kubota; Isemura
Bulletin of the Chemical Society of Japan, 1931 , vol. 6, p. 103,105
反应条件
1: aq.-ethanolic KOH-solution
2: 165 °C
3: 200 °C / 0.1 Torr / durch Erhitzen des Thorium-Salzes
View Scheme
参考文献
Kubota; Isemura
Bulletin of the Chemical Society of Japan, 1931 , vol. 6, p. 103,105
反应条件
1: 165 °C
2: 200 °C / 0.1 Torr / durch Erhitzen des Thorium-Salzes
View Scheme
参考文献
Kubota; Isemura
Bulletin of the Chemical Society of Japan, 1931 , vol. 6, p. 103,105
反应条件
sulfuric acid; nitric acid in water
T=0°C; 2 h;
参考文献
WARNER-LAMBERT COMPANY LLC
Patent: WO2004/69244 A1, 2004 ;
Location in patent: Page/Page column 79; 80 ;
