8-甲氧基-9-硼杂双环[3.3.1]壬烷合成路线 （共 45 条）
反应条件
(i) B2H6, THF, (ii) /BRN= 1098229/; Multistep reaction;
参考文献
Brown,H.C. et al.
Journal of the American Chemical Society, 1972 , vol. 94, p. 3561 - 3567
反应条件
in benzene-d6 T=20°C; 1 h; Inert atmosphere;
参考文献
Chakraborty, Sumit; Patel, Yogi J.; Krause, Jeanette A.; Guan, Hairong
Polyhedron, 2012 , vol. 32, # 1 p. 30 - 34
反应条件
in tetrahydrofuran byproducts: 5,7-dodecaene, NaCl, Zn; room temp.;
参考文献
Molander, Gary A.; Zinke, Paul W.
Organometallics, 1986 , vol. 5, p. 2161 - 2162
反应条件
in tetrahydrofuran byproducts: 2,2,7,7-tetramethyl-3,5-octadiene, NaCl, Zn; room temp.;
参考文献
Molander, Gary A.; Zinke, Paul W.
Organometallics, 1986 , vol. 5, p. 2161 - 2162
反应条件
in toluene T=-78 - 20°C; 2 h; Inert atmosphere;
参考文献
Takeuchi, Katsuhiko; Ichinohe, Masaaki; Sekiguchi, Akira
Organometallics, 2011 , vol. 30, # 7 p. 2044 - 2050
反应条件
1: toluene / 1 h / 20 °C / |Inert atmosphere 2: benzene-d6 / 8 h / 20 °C / 760.05 Torr View Scheme
参考文献
Chakraborty, Sumit; Zhang, Jie; Patel, Yogi J.; Krause, Jeanette A.; Guan, Hairong
Inorganic Chemistry, 2013 , vol. 52, # 1 p. 37 - 47
反应条件
1: tetrahydrofuran / 4 h / 20 °C / Inert atmosphere 2: toluene / 2 h / -78 - 20 °C / Inert atmosphere View Scheme
参考文献
Takeuchi, Katsuhiko; Ichinohe, Masaaki; Sekiguchi, Akira
Organometallics, 2011 , vol. 30, # 7 p. 2044 - 2050
反应条件
in toluene byproducts: ((i-Pr)(CH(SiMe3)2)2Si)2Si2D2HOMe; (Ar); addn. of MeOD by vac. transfer to toluene soln. of 1,1,4,4-tetrakis(bis(trimethylsilyl)methyl)-1,4-diisoproyl-2-(9-borabicyclo(3.3.1)nonan-9-yl)tetrasila-2-ene, stirring from -78°C to room temp. over 2 h; evapn. of solvent and MeOH, monitoring by NMR;
参考文献
Takeuchi, Katsuhiko; Ichinohe, Masaaki; Sekiguchi, Akira
Organometallics, 2011 , vol. 30, # 7 p. 2044 - 2050
反应条件
in toluene byproducts: ((i-Pr)(CH(SiMe3)2)2Si)2Si2H3OMe; (Ar); addn. of MeOH by vac. transfer to toluene soln. of 1,1,4,4-tetrakis(bis(trimethylsilyl)methyl)-1,4-diisoproyl-2-(9-borabicyclo(3.3.1)nonan-9-yl)tetrasila-2-ene, stirring from -78°C to room temp. over 2 h; evapn. of solvent and MeOH, monitoring by NMR;
参考文献
Takeuchi, Katsuhiko; Ichinohe, Masaaki; Sekiguchi, Akira
Organometallics, 2011 , vol. 30, # 7 p. 2044 - 2050
反应条件
in 1,2,5-trimethyl-benzene (C8H14B)2Se reacts in mesitylene at room temp. with B(OCH3)3 to a mixture of MeOBC8H14 and (MeO)2BSeBC8H14; identification by (11)B NMR;
参考文献
Koester, Roland; Seidel, Guenter; Yalpani, Mohamed
Chemische Berichte, 1989 , vol. 122, p. 1815 - 1824
