2-三甲基硅氧基-1,3-丁二烯合成路线 （共 28 条）
反应条件
triethylamine in tetrahydrofuran 3 h; Heating;
参考文献
Pennanen, Seppo I.
Synthetic Communications, 1985 , vol. 15, # 10 p. 865 - 872
反应条件
triethylamine in diethyl ether 1 h; Ambient temperature;
参考文献
Emde, Herbert; Goetz, Andreas; Hofmann, Karin; Simchen, Gerhard
Liebigs Annalen der Chemie, 1981 , # 9 p. 1643 - 1657
反应条件
triethylamine in N,N-dimethyl-formamide T=80 - 90°C; 18 h; Title compound not separated from byproducts;
参考文献
Uyeda, Roy T.; Vu, Phong; Holsworth, Daniel D.
Organic Preparations and Procedures International, 2002 , vol. 34, # 5 p. 540 - 543
反应条件
T=425°C; P=0.1 Torr;
参考文献
Corey, E. J.; Munroe, John E.
Journal of the American Chemical Society, 1982 , vol. 104, # 22 p. 6129 - 6130
反应条件
triethylamine; sodium iodide in acetonitrile T=100°C; 12 h; Yield given;
参考文献
Cazeau, Philippe; Moulines, Francoise; Laporte, Odile; Duboudin, Francoise
Journal of Organometallic Chemistry, 1980 , vol. 201, # 2 p. C9 - C13
反应条件
1: methyl vinyl ketone With HCo(CO)4 in dichloromethane T=-40°C; Reduction; 2: N,O-bis(trimethylsilyl) trifluoroacetamide in dichloromethane T=-30°C; silylation;
参考文献
Sisak, Attila
Journal of Organometallic Chemistry, 1999 , vol. 586, # 1 p. 48 - 53
参考文献
Ueda, Yasutsugu; Maynard, Susan C.
Tetrahedron Letters, 1985 , vol. 26, # 51 p. 6309 - 6312
反应条件
hydrogenchloride 1.) 150 deg C, 72 h; Multistep reaction;
参考文献
Ojima, Iwao; Yatabe, Momoko; Fuchikami, Takamasa
Journal of Organic Chemistry, 1982 , vol. 47, # 11 p. 2051 - 2055
反应条件
trifluoroacetic acid multistep reaction; <4+2> cycloaddition of various dienes with acceptor-substituted imines; other temperatures and other reaction times; Product distribution;
参考文献
Herdeis; Engel
Archiv der Pharmazie, 1992 , vol. 325, # 7 p. 411 - 417
反应条件
1: N-(tert-butoxycarbonyl)-2-ethoxy-1,2,3,4-tetrahydroquinoline With titanium tetrachloride in dichloromethane T=-30°C; activation; Cyclization; 0.166667 h; 2: 2-(trimethylsilyloxy)-1,3-butadiene in dichloromethane T=20°C; 0.5 h;
参考文献
Guarna; Machetti; Occhiato; Scarpi; Comerci, Alessandra; Danza, Giovanna; Mancina, Rosa; Serio, Mario; Hardy, Kimber
Journal of Medicinal Chemistry, 2000 , vol. 43, # 20 p. 3718 - 3735
