3'-甲氧基-2-联苯胺合成路线 （共 10 条）
反应条件
tetrakis(triphenylphosphine) palladium(0); potassium carbonate in ethanol; water; toluene
T=95°C; Suzuki cross-coupling; 16 h; Inert atmosphere;
参考文献
Liang, Zunjun; Feng, Ruokun; Yin, Hong; Zhang, Yuhong
Organic Letters, 2013 , vol. 15, # 17 p. 4544 - 4547
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethanol; water; benzene
T=80°C; Suzuki coupling; 12 h; Inert atmosphere;
参考文献
Xi, Jie; Dong, Qing-Li; Liu, Guan-Sai; Wang, Shaozhong; Chen, Lin; Yao, Zhu-Jun
Synlett, 2010 , # 11 p. 1674 - 1678
反应条件
1: With cesium fluoride in toluene; acetonitrile
T=110°C; 48 h; Inert atmosphereSealed vial;
2: With trifluoroacetic acid
T=20°C; 0.333333 h;
参考文献
Pirali, Tracey; Zhang, Fengzhi; Miller, Anna H.; Head, Jenna L.; McAusland, Donald; Greaney, Michael F.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1006 - 1009
反应条件
1.1: triethylamine / dichloromethane / 20 °C
2.1: cesium fluoride / toluene; acetonitrile / 48 h / 110 °C / Inert atmosphere; Sealed vial
2.2: 0.33 h / 20 °C
View Scheme
参考文献
Pirali, Tracey; Zhang, Fengzhi; Miller, Anna H.; Head, Jenna L.; McAusland, Donald; Greaney, Michael F.
Angewandte Chemie - International Edition, 2012 , vol. 51, # 4 p. 1006 - 1009
反应条件
2,2'-azo-bisisobutyronitrile; diphenyl diselenide; tri-n-butyl-tin hydride
1 h; Heating;
参考文献
Crich, David; Patel, Mitesh
Tetrahedron, 2006 , vol. 62, # 33 p. 7824 - 7837
反应条件
1: Cu-Sn / 200 - 240 °C
2: (catalytic hydrogenation)
View Scheme
参考文献
Oki,M.; Iwamura,H.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1395 - 1401
反应条件
1: Cu-Sn / 200 - 240 °C
2: (catalytic hydrogenation)
View Scheme
参考文献
Oki,M.; Iwamura,H.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1395 - 1401
反应条件
(catalytic hydrogenation);
参考文献
Oki,M.; Iwamura,H.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1395 - 1401
反应条件
Cp*Rh(OTf)2; copper diacetate; potassium carbonate; 4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in o-xylene
T=130°C; 24 h; Inert atmosphere;
参考文献
Jiang, Qibai; Duan-Mu, Dandan; Zhong, Wei; Chen, Hao; Yan, Hong
Chemistry - A European Journal, 2013 , vol. 19, # 6 p. 1903 - 1907
反应条件
(i) (diazotization), (ii) (hydrolysis); Multistep reaction;
参考文献
Oki,M.; Iwamura,H.
Bulletin of the Chemical Society of Japan, 1961 , vol. 34, p. 1395 - 1401
