1,3,5,7,9,11,13,15-八环己基并五环八硅氧烷合成路线 (共 7 条)
反应条件
hydrogen; palladium on activated charcoal in acetic acid; ethyl acetate
T=200°C; P=25840 Torr;
参考文献
Feher, Frank J.; Budzichowski, Theodore A.
Journal of Organometallic Chemistry, 1989 , vol. 373, p. 153 - 164
反应条件
tetrabutyl ammonium fluoride in dichloromethane
T=20°C; 16 h;
参考文献
Bassindale, Alan R.; Liu, Zhihua; Parker, David J.; Taylor, Peter G.; Horton, Peter N.; Hursthouse, Michael B.; Light, Mark E.
Journal of Organometallic Chemistry, 2003 , vol. 687, # 1 p. 1 - 11
反应条件
tetrabutyl ammonium fluoride in dichloromethane
T=20°C; 16 h;
参考文献
Bassindale, Alan R.; Liu, Zhihua; Parker, David J.; Taylor, Peter G.; Horton, Peter N.; Hursthouse, Michael B.; Light, Mark E.
Journal of Organometallic Chemistry, 2003 , vol. 687, # 1 p. 1 - 11
反应条件
tetrabutyl ammonium fluoride in dichloromethane
T=20°C; 16 h;
参考文献
Bassindale, Alan R.; Liu, Zhihua; Parker, David J.; Taylor, Peter G.; Horton, Peter N.; Hursthouse, Michael B.; Light, Mark E.
Journal of Organometallic Chemistry, 2003 , vol. 687, # 1 p. 1 - 11
反应条件
water; triethylamine in diethyl ether
参考文献
Feher, Frank J.; Soulivong, Daravong; Eklund, Andrew G.
Chemical Communications, 1998 , # 3 p. 399 - 400
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran; dichloromethane; water
24 h;
参考文献
Bassindale, Alan R.; Chen, Huiping; Liu, Zhihua; MacKinnon, Iain A.; Parker, David J.; Taylor, Peter G.; Yang, Yuxing; Light, Mark E.; Horton, Peter N.; Hursthouse, Michael B.
Journal of Organometallic Chemistry, 2004 , vol. 689, # 21 p. 3287 - 3300
反应条件
Hydrolysis.und anschliessenden Erhitzen mit NaOH auf 340-440 gradC;
参考文献
Barry et al.
Journal of the American Chemical Society, 1955 , vol. 77, p. 4248,4251