HCl is passed over KClO3;; mixture of ClO2 and Cl2 is obtained;;
参考文献
Pebal
Liebigs Annalen der Chemie, 1875 , vol. 177, p. 1 - 1
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Schacherl
Liebigs Annalen der Chemie, 1876 , vol. 182, p. 193 - 193
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Gmelin Handbook: Cl: MVol., 1, page 5 - 7
in neat (no solvent) byproducts: O2; transport reaction: passing F2-N2 mixture over KClO3 at 25 - 60°C;; washing with NaOH; passing ClO3F through Na2S2O3 soln.; drying over NaOH and P2O5;;
参考文献
Engelbrecht, A.; Atzwanger, H.
Journal of Inorganic and Nuclear Chemistry, 1956 , vol. 2, p. 348 - 357
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Gmelin Handbook: Cl: SVol.B2, 125, page 579 - 581
iron(II) sulfate no reaction between dry KClO3 and complete anhydrous FeSO4 at 100 °C; evolution of Cl and ClO2 by moistening the mixture with some drops of water or by use of mercatile FeSO4;;
参考文献
Herschkowitsch, M.
Z. Anorg. Chem., 1922 , vol. 125, p. 148 - 148
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Gmelin Handbook: Fe: MVol.B2, 39, page 398 - 400