环戊基铁(II) 二羰基二聚体合成路线 （共 74 条）
反应条件
zinc in further solvent(s) under pressure in dicyclohexylamine at 120°C;;
参考文献
Gmelin Handbook: V: MVol.B1, 130, page 338 - 340
反应条件
sodium amalgam in tetrahydrofuran under N2, addn. of MeSSMe to soln. of Fe complex and sodium amalgan in THF; stirring for 1 h; filtration; evapn.; extn. of residue with hexane; partial evapn.; Chromy. (silica gel, Benzene, acetone); evapn. of acetone; crystn. with pentene;
参考文献
Treichel, P. M.; Schmidt, M. S.; Nakagaki, P. C.; Rublein, E. K.
Journal of Organometallic Chemistry, 1986 , vol. 311, p. 193 - 198
反应条件
in acetonitrile-D3 N2-atmosphere; slight excess Fe-complex; product mixt. not sepd., detd. by NMR spectroscopy;
参考文献
Treichel; Rublein
Journal of Organometallic Chemistry, 1996 , vol. 512, # 1-2 p. 157 - 164
反应条件
in solid matrix byproducts: CO; thermal decompn. of Na-zeolithe absorbed Fe complex at 410 K in vac.; detected by MAS and TPD-MS spectroscopy;
参考文献
Moller; Borvornwattananont; Bein
Journal of physical chemistry, 1989 , vol. 93, # 11 p. 4562 - 4571
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
thionyl chloride in tetrahydrofuran
THF soln. of SOCl2 was slowly added to a soln. of (CpFe(CO)2)2 in THF at room temp. under N2 atmosphere, mixt. was stirred for 30 min; solvent was removed under vac., residue recrystd. from CH2Cl2/n-hexane;elem. anal.;
参考文献
El-Hinnawi, Mahmoud A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1987 , vol. 17, p. 191 - 200
反应条件
tetrachloromethane in tetrahydrofuran
Irradiation (UV/VIS); irradn. of Fe complex and phosphite ligand in THF at -78°C, CCL4vac. distd. in soln., warmed to room temp.; not isolated, detected by IR;
参考文献
Tyler, David R.; Schmidt, Maryke A.; Gray, Harry B.
Journal of the American Chemical Society, 1983 , vol. 105, # 19 p. 6018 - 6021
反应条件
SO2Cl2 in tetrahydrofuran
byproducts: CO; Room temp., N2-atmosphere.;
参考文献
Manning, A. R.; McNally, Gerard; Cunningham, Desmond; McArdle, Patrick; Simmie, John M.
Journal of Organometallic Chemistry, 1988 , vol. 338, p. 383 - 392
反应条件
in not given
Irradiation (UV/VIS); irradn. in alkane soln. (Ar; λ>500nm); further product (6 IR bands) believed to be the radical coupling product from (η5-C5H5)Fe(CO)2 and (η1-C5Cl4)Mn(CO)5;
参考文献
Young; Wrighton
Journal of the American Chemical Society, 1990 , vol. 112, # 1 p. 157 - 166
