环戊基铁(II) 二羰基二聚体合成路线 （共 74 条）
反应条件
4-(N,N-dimethlyamino)pyridine; palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene in toluene
T=110°C; 1 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
CO in dichloromethane; acetonitrile
dissolving dimer in CH2Cl2 : CH3CN 1:1; bubbling CO through soln.; adding an excess of NOPF6 in several portions (N2-atmosphere); color changedfrom deep brown to yellow brown; crystn.; removing solvents; washing (ether); extn. (acetone); filtration in air; pptn. by addn. of Et2O at -20°C;
参考文献
Singh, Mono M.; Angelici, Robert J.
Inorganic Chemistry, 1984 , vol. 23, p. 2691 - 2698
反应条件
aluminium trichloride; bromine in decalin
The soln. of complex and AlCl3 in decalin was heated to 100°C under N2 atm., Br2 was added, stirred for 10 min, heated with stirring for3 h at 150°C, cooled to about 30°C; water layer was addeda soln. of NH4PF6 in water;; ppt. was filtered, dissolved in CH3NO2, dried over MgSO4, concd., Et2O was added; elem. anal.;;
参考文献
Gill, U. S.; Lee, C. C.; Sutherland, R. G.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1984 , vol. 14, p. 953 - 956
反应条件
in tetrahydrofuran
addn. of AgPF6*2C4H8O2 to soln. of complex in dried and distilled solvent, molar ratio of educts: AgPF6/complex=2/1, 2h, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
