环戊基铁(II) 二羰基二聚体合成路线 （共 74 条）
反应条件
in acetonitrile
addn. of AgPF6*2C4H8O2 to soln. of complex in dried and distilled solvent, molar ratio of educts: AgPF6/complex=2/1, <30s, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
palladium diacetate; 1,8-diazabicyclo[5.4.0]undec-7-ene; tri-cyclo-hexyl-phosphine in toluene
T=110°C; 12 h;
参考文献
Nakaya, Ryotaro; Yorimitsu, Hideki; Oshima, Koichiro
Chemistry Letters, 2011 , vol. 40, # 9 p. 904 - 906
反应条件
silver nitrate; triphenylphosphine in tetrahydrofuran
addn. of AgNO3 to soln. of complex and PPh3 in dried and distilled solvent, ratio of educts: AgNO3/complex/PPh3=2/1/2, 24h, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
silver nitrate in acetonitrile
addn. of AgNO3 to soln. of complex in dried and distilled solvent, ratio of educts: AgNO3/complex=2/1, <30s, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
silver nitrate; triphenylphosphine in acetonitrile
addn. of AgNO3 to soln. of complex and PPh3 in dried and distilled solvent, ratio of educts: AgNO3/complex/PPh3=2/1/2, 2h, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
in dichloromethane
addn. of AgBF4*0.5C4H8O2 to soln. of complex in dried and distilled solvent, molar ratio of educts: AgBF4/complex=2/1, 2h, darkness, room temp., pptd. Ag filtered off, solvent removed at reduced press.; product recrystd. from dichloromethane/pentane, reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
silver nitrate in acetonitrile
addn. of AgNO3 to soln. of complexes in dried and distilled solvent, ratio of educts: (Fe2(η-C5H5)2(CO)4)/(Fe2(η-C5H5)2(CO)2(CNMe)2)/AgNO3=1/1/1, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
triphenylphosphine in acetonitrile
addn. of AgBF4*0.5C4H8O2 to soln. of complex and PPh3 in dried and distilled solvent, molar ratio of educts: AgBF4/complex/PPh3=2/1/2, >3h, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
in tetrahydrofuran
addn. of AgPF6*2C4H8O2 to soln. of complex in dried and distilled solvent, molar ratio of educts: AgPF6/complex=2/1, 2h, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
in acetonitrile
addn. of AgBF4*0.5C4H8O2 to soln. of complex in dried and distilled solvent, molar ratio of educts: AgBF4/complex=2/1, <30s, darkness, room temp.; sepn. of products by chromy. (alumina/dichloromethane), products recrystd. from dichloromethane/pentane, reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
