环戊基铁(II) 二羰基二聚体合成路线 （共 74 条）
反应条件
in acetonitrile
addn. of AgPF6*2C4H8O2 to soln. of complex in dried and distilled solvent, molar ratio of educts: AgPF6/complex=2/1, <30s, darkness, room temp.; reaction detected by IR;
参考文献
Callan, Brian; Manning, A. R.; Stephens, F. S.
Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 357 - 378
反应条件
in neat (no solvent)
byproducts: iron; flash vac. pyrolysis at temp. more than 500°C; ferrocene was the only molecular product;
参考文献
Glidewell, Christopher; McKechne, James S.
Journal of Organometallic Chemistry, 1987 , vol. 321, p. C21 - C23
反应条件
hydrazine in chloroform
byproducts: CO; Irradiation (UV/VIS); N2-atmosphere; irradiation of Fe-complex (Spectroline 100 UV lamp, roomtemp., 5 h, pptn.), partial evapn., hydrazine addn.; chromy. (Al2O3, CHCl3/benzene=4:1 v/v);
参考文献
Landon, Shayne J.; Rheingold, Arnold L.
Inorganica Chimica Acta, 1981 , vol. 47, p. 187 - 190
反应条件
P(C6H5)3 in decalin
(argon); reflux (10 min); filtration, evapn. (vac.), addn. of Et2O and Al2O3, drying to free-flowing, chromy. (Al2O3; Et2O/CH2Cl2); elem. anal.;
参考文献
Scherer, Otto J.; Kemeny, Gunther; Wolmershaeuser, Gotthelf
Chemische Berichte, 1995 , vol. 128, # 12 p. 1145 - 1148
反应条件
in toluene
under inert atmosphere; toluene added to mixt. of NH4(P(OEt)2Se2) and Fecomplex; refluxed in oil bath for 4 h with stirring; filtered hot; filtrate evapd. to dryness; purified by column chromy. (silica gel, hexane-ethyl acetate 10:1); second band collected; solvent evapd.; elem. anal.;
参考文献
Chiou, Ling-Song; Fang, Ching-Shiang; Sarkar, Bijay; Liu, Ling-Kang; Leong, Max K.; Liu
Organometallics, 2009 , vol. 28, # 17 p. 4958 - 4963
反应条件
in toluene
under inert atmosphere; toluene added to mixt. of NH4(P(O-n-Pr)2Se2) andFe complex; refluxed in oil bath for 4 h with stirring; filtered hot; filtrate evapd. to dryness; purified by column chromy. (silica gel, hexane-ethyl acetate 10:1); second band collected; solvent evapd.; elem. anal.;
参考文献
Chiou, Ling-Song; Fang, Ching-Shiang; Sarkar, Bijay; Liu, Ling-Kang; Leong, Max K.; Liu
Organometallics, 2009 , vol. 28, # 17 p. 4958 - 4963
反应条件
in 1,3,5-trimethyl-benzene
refluxed for 50 h under N2; evapd., products were sepd. by chromy. on Al2O3 (7percent H2O, eluent pentane followed by pentane-CH2Cl2), CpFe(C4H4BPh)Co(C4H4BPh) was recrystd. from CH2Cl2-hexane; elem. anal. for the latter complex;
参考文献
Herberich, G. E.; Hessner, B.; Saive, R.
Journal of Organometallic Chemistry, 1987 , vol. 319, p. 9 - 28
反应条件
in 1,3,5-trimethyl-benzene
(N2); soln. of both iron complexes was kept at 160°C for 4 h; solvent was removed in high vac., distn. (50°C, 0,01 Torr) gave tricarbonyl complex and ferrocene; diiron complex was sublimed out at 120°C/0,01 Torr;
参考文献
Edwin, Joseph; Siebert, Walter; Kruegger, Carl
Journal of Organometallic Chemistry, 1985 , vol. 282, p. 297 - 304
反应条件
in not given
under Ar or N2; not isolated;
参考文献
Goldman, Alan S.; Tyler, David R.
Inorganic Chemistry, 1987 , vol. 26, p. 253 - 258
反应条件
in not given
under Ar or N2; not isolated;
参考文献
Goldman, Alan S.; Tyler, David R.
Inorganic Chemistry, 1987 , vol. 26, p. 253 - 258
