2-三氟甲基-1,1,1,3,3,3-六氟丙烷合成路线 （共 44 条）
反应条件
triethylsilane in benzene-d6
T=24.9°C; 22 h; Irradiationreactivity of perfluoroisopropyl and perfluoro-tert-butyl radicals towards H-atom abstraction from Et3Si; competition experiments; formation of addition product and reduction product; mechanism; Rate constantProduct distribution;
参考文献
Dolbier Jr., William R.; Li, An-Rong
Journal of the Chemical Society. Perkin Transactions 2, 1998 , # 1 p. 79 - 82
反应条件
in diethylene glycol dimethyl ether
参考文献
Del'tsova, D. P.; Zeifman, Yu. V.; Gambaryan, N. P.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1985 , vol. 34, # 11 p. 2345 - 2350
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1985 , # 11 p. 2533 - 2537
参考文献
Del'tsova, D. P.; Safronova, Z. V.; Gambaryan, N. P.; Knunyants, N. L.
Doklady Chemistry, 1982 , vol. 267, p. 437 - 440
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 267, # 4 p. 856 - 859
反应条件
hydrogenchloride
1) CH3CN, 24 h; Yield given. Multistep reaction;
参考文献
Zeifman, Yu. V.; Postovoi, S. A.; Knunyants, I. L.
Doklady Chemistry, 1982 , vol. 265, p. 212 - 215
Dokl. Akad. Nauk SSSR Ser. Khim., 1982 , vol. 265, # 2 p. 347 - 351
反应条件
in acetonitrile
1.) -78 deg C, 2 h, 2.) from 55 deg C to 60 deg C, 4 h; Further byproducts given. Title compound not separated from byproducts;
参考文献
Munavalli, S.; Lewis, E. O.; Muller, A. J.; Rossman, D. I.; Rohrbaugh, D. K.; Ferguson, C. P.
Journal of Fluorine Chemistry, 1993 , vol. 63, # 3 p. 253 - 264
反应条件
T=20°C; 16 h; Title compound not separated from byproducts;
参考文献
Del'tsova, D. I.; Gambaryan, N. P.
Russian Chemical Bulletin, 1993 , vol. 42, # 2 p. 333 - 336
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1993 , # 2 p. 372 - 374
反应条件
in acetonitrile
T=20°C; 3 h; further ylides; Product distributionMechanism;
参考文献
Zeifman, Yu. V.; Lantseva, L. T.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1983 , vol. 32, # 9 p. 1941 - 1943
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1983 , # 9 p. 2149 - 2151
反应条件
potassium fluoride; iodine cloride in sulfolane
参考文献
Ponomarev, V. F.; Podsevalov, P. V.; Nazarenko, T. I.; Deev, L. E.; Pashkevich, K. I.
Journal of Organic Chemistry USSR (English Translation), 1990 , vol. 26, # 6 p. 1179 - 1180
Zhurnal Organicheskoi Khimii, 1990 , vol. 26, # 6 p. 1365 - 1366
参考文献
Knunyants,I.L. et al.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1966 , p. 1008 - 1012
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1966 , # 6 p. 1057 - 1062
反应条件
cesium fluoride in diethylene glycol dimethyl ether
50 h; Ambient temperature;
参考文献
Solov'ev, D. V.; Rodin, A. A.; Zenkevich, I. G.; Lavrent'ev, A. A.
J. Gen. Chem. USSR (Engl. Transl.), 1988 , vol. 58, # 7 p. 1544 - 1550,1373 - 1378
