环氧十五烷-2,13-二酮合成路线 （共 15 条）
反应条件
hydrogenchloride; zinc in acetic anhydride T=0 - 5°C; 1 h;
参考文献
Zakharkin, L. I.; Pryanishnikov, A. P.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 2 p. 262 - 263
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 2 p. 296 - 298
反应条件
hydrogenchloride; mercury; zinc in toluene
参考文献
Zakharkin,L.I. et al.
Journal of Organic Chemistry USSR (English Translation), 1979 , vol. 15, p. 1285 - 1290
Zhurnal Organicheskoi Khimii, 1979 , vol. 15, p. 1441 - 1447
反应条件
sodium borohydride in methanol; water
参考文献
Haarmann and Reimer GmbH
Patent: US5319104 A1, 1994 ;
反应条件
ammonium cerium(IV) nitrate; triethylamine in acetonitrile
48 h; Heating;
参考文献
Cookson, Richard C.; Ray, Partha S.
Tetrahedron Letters, 1982 , vol. 23, # 34 p. 3521 - 3524
反应条件
sodium hydrogensulfite in ethanol; water
5 h; Heating;
参考文献
Mahajan, Jaswant Rai; Araujo, Hugo Clemente
Synthesis, 1980 , # 1 p. 64 - 66
反应条件
1: 80 percent / hydrogen, aq. conc. HCl / PtO2 / ethanol / 24 h / 2280 Torr
2: 97 percent / KHCO3 / methanol / 96 h
3: 64 percent / NaH, 4 Angstroem molecular sieves / dimethylformamide / 1.5 h / 20 °C
4: O3 / CH2Cl2; methanol / 1 h
View Scheme
参考文献
Milenkov, Branimir; Guggisberg, Armin; Hesse, Manfred
Helvetica Chimica Acta, 1987 , vol. 70, p. 760 - 765
反应条件
1: 91 percent / NaBH4 / methanol / 0.17 h
2: 80 percent / hydrogen, aq. conc. HCl / PtO2 / ethanol / 24 h / 2280 Torr
3: 97 percent / KHCO3 / methanol / 96 h
4: 64 percent / NaH, 4 Angstroem molecular sieves / dimethylformamide / 1.5 h / 20 °C
5: O3 / CH2Cl2; methanol / 1 h
View Scheme
参考文献
Milenkov, Branimir; Guggisberg, Armin; Hesse, Manfred
Helvetica Chimica Acta, 1987 , vol. 70, p. 760 - 765
反应条件
1: 95 percent / H2 / 10 percent Pd/C / ethanol / 3 h / 2280 Torr
2: O3 / CH2Cl2; methanol / 1 h
View Scheme
参考文献
Milenkov, Branimir; Guggisberg, Armin; Hesse, Manfred
Helvetica Chimica Acta, 1987 , vol. 70, p. 760 - 765
反应条件
1: 91 percent / m-chloroperbenzoic acid / CHCl3 / 0.5 h / 0 °C
2: 95 percent / H2 / 10 percent Pd/C / ethanol / 3 h / 2280 Torr
3: O3 / CH2Cl2; methanol / 1 h
View Scheme
参考文献
Milenkov, Branimir; Guggisberg, Armin; Hesse, Manfred
Helvetica Chimica Acta, 1987 , vol. 70, p. 760 - 765
反应条件
1: N,N-diisopropylethylamine, Tf2O / CH2Cl2 / 1.) -78 deg C, 5 h, 2.) from -78 deg C to 0 deg C, 3.) 12 h, RT
2: 1.) N,N-diisopropylethylamine, Tf2O, 2.) O3, 3.) Me2S
View Scheme
参考文献
Hanaki, Naoyuki; Ishihara, Kazuaki; Kaino, Makoto; Naruse, Yuji; Yamamoto, Hisashi
Tetrahedron, 1996 , vol. 52, # 21 p. 7297 - 7320
