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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
4-碘三苯胺
合成路线
(共 9 条)
624-38-4
1,4-二碘苯
+
122-39-4
二苯胺
→
反应条件
38257-52-2
4-碘三苯胺
反应条件
18-crown-6 ether; copper; potassium carbonate in 1,2-dichloro-benzene T=0 - 20°C; Ullmann Condensation; 64 h; Reflux;
参考文献
Amro, Kassem; Daniel, Jonathan; Clermont, Guillaume; Bsaibess, Talia; Pucheault, Mathieu; Genin, Emilie; Vaultier, Michel; Blanchard-Desce, Mireille
Tetrahedron, 2014 , vol. 70, # 10 p. 1903 - 1909
624-38-4
1,4-二碘苯
+
90-30-2
N-苯基-1-萘胺
→
反应条件
38257-52-2
4-碘三苯胺
反应条件
copper(II) oxide in various solvent(s) T=160°C; 16 h;
参考文献
Paine, Anthony James
Journal of the American Chemical Society, 1987 , vol. 109, # 5 p. 1496 - 1502
36809-26-4
4-溴三苯胺
→
反应条件
38257-52-2
4-碘三苯胺
反应条件
1: With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 0.5 h; Inert atmosphere; 2: With iodine in tetrahydrofuran; hexane T=-78 - 20°C; Inert atmosphere;
参考文献
Fang, Jing-Kun; An, De-Lie; Wakamatsu, Kan; Ishikawa, Takeharu; Iwanaga, Tetsuo; Toyota, Shinji; Matsuo, Daisuke; Orita, Akihiro; Otera, Junzo
Tetrahedron Letters, 2010 , vol. 51, # 6 p. 917 - 920
591-50-4
碘苯
+
38257-52-2
4-碘三苯胺
+
122-39-4
二苯胺
→
反应条件
14118-16-2
1,4-双(二苯基氨基)苯
+
603-34-9
三苯胺
反应条件
potassium hydroxide; copper T=160°C; competitive reaction, var. catalysts; Rate constantMechanism;
参考文献
Paine, Anthony James
Journal of the American Chemical Society, 1987 , vol. 109, # 5 p. 1496 - 1502
2039-82-9
4-溴苯乙烯
+
38257-52-2
4-碘三苯胺
→
反应条件
219987-44-7
反应条件
tetrabutylammomium bromide; palladium diacetate in N,N-dimethyl-formamide T=60°C; Heck Reaction; 36 h; Inert atmosphereAlkaline conditions;
参考文献
Ji, Changyan; Yin, Lunxiang; Wang, Lihui; Jia, Tao; Meng, Shixiang; Sun, Yingji; Li, Yanqin
Journal of Materials Chemistry C, 2014 , vol. 2, # 20 p. 4019 - 4026
38257-52-2
4-碘三苯胺
+
1066-54-2
三甲基乙炔基硅
→
反应条件
205877-26-5
4-乙炔基三苯胺
反应条件
1: With palladium 2: With potassium fluoride in tetrahydrofuran; methanol
参考文献
Lee, Changjin; Kang, Yongku; Lee, Sungkoo; Kim, Hee Jung; Jung, Sang Hyun; Kim, Jeong-Soo
Molecular Crystals and Liquid Crystals Science and Technology, Section A: Molecular Crystals and Liquid Crystals, 2001 , vol. 370, p. 207 - 210
38257-52-2
4-碘三苯胺
→
反应条件
205877-26-5
4-乙炔基三苯胺
反应条件
1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / 50 °C / |Inert atmosphere 2: potassium hydroxide; water / tetrahydrofuran; methanol View Scheme
参考文献
Nguyen, Quynh Pham Bao; Hwang, Hee Min; Song, Mi-Seon; Song, Hui Jeong; Kim, Gyeong Heon; Kwon, Jang Hyuk; Shim, Na Young; Chai, Kyu Yun
Bulletin of the Korean Chemical Society, 2014 , vol. 35, # 4 p. 1247 - 1250
591-50-4
碘苯
+
38257-52-2
4-碘三苯胺
+
122-39-4
二苯胺
→
反应条件
14118-16-2
1,4-双(二苯基氨基)苯
+
603-34-9
三苯胺
反应条件
potassium hydroxide; copper T=160°C; competitive reaction, var. catalysts; Rate constantMechanism;
参考文献
Paine, Anthony James
Journal of the American Chemical Society, 1987 , vol. 109, # 5 p. 1496 - 1502
38257-52-2
4-碘三苯胺
+
5905-36-2
N,N'-二苯基间苯二胺
→
反应条件
反应条件
copper(l) iodide; n-butyllithium 1.) hexane, diphenyl ether, 15 min, room temperature, 2.) 200 deg C, 48 h.; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Wienk; Janssen
Journal of the American Chemical Society, 1997 , vol. 119, # 19 p. 4492 - 4501