lithium bromide; tris-(dimethylamino)-phosphine in toluene T=20°C; 3.33 h; RefluxInert atmosphere;

1.1: dihydrogen peroxide / methanol; water / 0.83 h / 20 °C 1.2: 3.75 h / 15 - 20 °C 2.1: sodium tetrahydroborate / methanol / 3.75 h / 0 - 20 °C / |Inert atmosphere 3.1: lithium bromide; tris-(dimethylamino)-phosphine / toluene / 3.33 h / 20 °C / |Reflux; |Inert atmosphere View Scheme

in toluene 2 h; Heating;

N,N,N',N',N'',N''-hexamethylphosphoric triamide; lithium bromide in toluene 0.5 h; Heatingvar. epoxycyclohexanols; other solubilizing agents; other solvents and time; Product distributionMechanism;