aluminium trichloride in dichloromethane T=0°C; 0.333333 h; Yield given;

2: 95 percent / 20percent aq. KOH / ethanol / 48 h / Heating 3: thionyl chloride (SOCl2) / 1 h / Heating 4: AlCl3 / CH2Cl2 / 0.33 h / 0 °C View Scheme

1: 95 percent / 20percent aq. KOH / ethanol / 48 h / Heating 2: thionyl chloride (SOCl2) / 1 h / Heating 3: AlCl3 / CH2Cl2 / 0.33 h / 0 °C View Scheme

暂无反应条件数据

palladium on activated charcoal; 1-methyl-naphthalene

1: 84 percent / NaBH4 / methanol / 0 °C 2: 100 percent / p-toluenesulfonic acid / benzene / 2 h / Heating 3: 1.) I2 / 1.) C6H6, 2.) overnight 4: 48 percent / o-chloranil / dioxane / Heating; overnight 5: 83 percent / 1 N NaOMe / tetrahydrofuran; methanol / 1 h / -20 °C 6: 66 percent / 99percent m-chloroperoxybenzoic acid / CHCl3 / 1 h / 0 °C View Scheme

1: 83 percent / LiAlH4 / diethyl ether / 1 h / Heating; 1.) 20 deg C, 2.) 1 h, reflux 2: 75 percent / p-TsOH / benzene / 4 h / Heating 3: 1.) I2 / 1.) C6H6, reflux; room temp. 2.) 3 h, reflux View Scheme

1: 25 percent / ammonium nitrate, trifluoroacetic anhydride / acetonitrile / Ambient temperature 2: NaBH4 / CH2Cl2; methanol / 2 h / Ambient temperature 3: p-toluenesulfonic acid / toluene / 3 h / Heating 4: 56 percent / dichlorodicyanobenzoquinone (DDQ) / toluene / 2 h / Heating 5: 96 percent / hydrazine monohydrate / Raney Ni / ethanol / 2 h / Heating View Scheme