1-三甲基硅烷-1-己炔合成路线 （共 85 条）
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; Yb-imine; methyl iodide in tetrahydrofuran 17 h; Ambient temperature;
参考文献
Bulletin de la Societe Chimique de France, , vol. 134, # 3-4 p. 349 - 356
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; Yb-imine; methyl iodide in tetrahydrofuran 17 h; Ambient temperature;
参考文献
Makioka, Yoshikazu; Taniguchi, Yuki; Kitamura, Tsugio; Fujiwara, Yuzo; Saiki, Akira; Takaki, Ken
Bulletin de la Societe Chimique de France, 1997 , vol. 134, # 3-4 p. 349 - 356
反应条件
2: Br2 / CH2Cl2; CCl4 3: Na / methanol / 24 h / Ambient temperature 4: (i) tBuLi, THF, ether, pentane, (ii) /BRN= 385735/, (iii) aq. AcOH View Scheme
参考文献
Neumann,H.; Seebach,D.
Chemische Berichte, 1978 , vol. 111, p. 2785 - 2812
反应条件
indium(III) chloride; sodium tetrahydroborate in tetrahydrofuran T=-15 - 20°C; Title compound not separated from byproducts;
参考文献
Wang, Chunyan; Yan, Lei; Zheng, Zhiguo; Yang, Deyu; Pan, Yuanjiang
Tetrahedron, 2006 , vol. 62, # 33 p. 7712 - 7717
反应条件
hydrogenchloride 1.) CHCl3, 0 deg C, 3 h, 2.) acetone, reflux, 5 min; Yield given. Multistep reaction;
参考文献
Page, Philip C. Bulman; Rosenthal, Stephen; Williams, Richard Vaughan
Synthesis, 1988 , # 8 p. 621 - 623
反应条件
1: 79 percent / PdCl2(PhCN)2 / Ambient temperature 2: 57 percent / Bu4NF / tetrahydrofuran View Scheme
参考文献
Yamaguchi, Ryohei; Kawasaki, Hiroshi; Yoshitome, Toshihide; Kawanisi, Mituyosi
Chemistry Letters, 1982 , p. 1485 - 1486
反应条件
potassium carbonate; AgCl; tetrakis(triphenylphosphine) palladium(0) in methanol; N,N-dimethyl-formamide T=40°C;
参考文献
Halbes, Ulla; Pale, Patrick
Tetrahedron Letters, 2002 , vol. 43, # 11 p. 2039 - 2042
反应条件
copper(l) chloride in benzene 1 h; Heating;
参考文献
Tetrahedron Letters, , vol. 37, # 23 p. 4051 - 4054
反应条件
tetrabutyl ammonium fluoride in tetrahydrofuran T=20°C; 0.25 h; Inert atmosphere;
参考文献
Chintareddy, Venkat Reddy; Wadhwa, Kuldeep; Verkade, John G.
Journal of Organic Chemistry, 2011 , vol. 76, # 11 p. 4482 - 4488
反应条件
1,3-dimethyl-imidazolidin-2-one; 1-chloro-pent-2-yne; copper(l) chloride
T=80°C; 2 h;
参考文献
Montel, Florian; Beaudegnies, Renaud; Kessabi, Jilali; Martin, Benjamin; Muller, Eric; Wendeborn, Sebastian; Jung, Pierre M. J.
Organic Letters, 2006 , vol. 8, # 9 p. 1905 - 1908
