3-(全氟正己基)环氧丙烷合成路线 （共 15 条）
反应条件
potassium hydroxide in methanol; water T=6°C; 3 h;
参考文献
Taylor, Charles Kenneth; Michalczyk, Michael Joseph; Acosta, Erick Jose
Patent: US2009/42996 A1, 2009 ;
Location in patent: Page/Page column 7 ;
反应条件
potassium hydroxide; silica gel in hexane 1 h; Heating;
参考文献
Cirkva, Vladimir; Polak, Radek; Paleta, Oldrich; Kefurt, Karel; Moravcova, Jitka; Kodicek, Milan; Forman, Stanislav
Carbohydrate Research, 2004 , vol. 339, # 13 p. 2177 - 2185
反应条件
potassium hydroxide in hexane 2 h; Heating; Yields of byproduct given;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
potassium hydroxide; 2,2'-azo-bisisobutyronitrile in 1,2-dichloro-ethane T=70°C; Substitution; Cyclization; Dimerization; 2 h;
参考文献
Rubio; Blancou; Commeyras
Journal of Fluorine Chemistry, 2000 , vol. 106, # 1 p. 1 - 5
反应条件
1: 95 percent Chromat. / dibenzoyl peroxide / 172 °C 2: 57 percent / KOH / hexane / 16 h / Heating View Scheme
参考文献
Guyot, Bernard; Ameduri, Bruno; Boutevin, Bernard
Journal of Fluorine Chemistry, 1995 , vol. 74, # 2 p. 233 - 240
反应条件
potassium hydroxide in diethyl ether 6 h; Heating; Yields of byproduct given;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
potassium hydroxide; 2,6-di-t-butyl-4-methyl-phenol 2.) hexane, reflux, 3 h; Yield given. Multistep reaction;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
potassium hydroxide; 2,6-di-t-butyl-4-methyl-phenol 2.) Et2O, reflux, 6 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 83, # 2 p. 151 - 158
反应条件
boron trifluoride diethyl etherate in di-isopropyl ether T=95°C; 11 h;
参考文献
Collection of Czechoslovak Chemical Communications, , vol. 66, # 11 p. 1665 - 1681
反应条件
1: 95 percent / BF3*Et2O / 0.5 h / Heating 2: 96 percent / aq. HCl, MeOH / 2 h / Heating View Scheme
参考文献
Cirkva, Vladimir; Ameduri, Bruno; Boutevin, Bernard; Paleta, Oldrich
Journal of Fluorine Chemistry, 1997 , vol. 84, # 1 p. 53 - 61
