2-(4-硝基苯基)-4,4,5,5-四甲基咪唑啉-3-氧化物-1-氧基合成路线 （共 9 条）
反应条件
tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide in dichloromethane
T=20°C; 1 h;
参考文献
Gorini, Lapo; Caneschi, Andrea; Menichetti, Stefano
Synlett, 2006 , # 6 p. 948 - 950
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
Inert atmosphereReflux;
参考文献
Tanimoto, Ryu; Suzuki, Shuichi; Kozaki, Masatoshi; Okada, Keiji
Chemistry Letters, 2014 , vol. 43, # 5 p. 678 - 680
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
Inert atmosphereReflux;
参考文献
Tanimoto, Ryu; Suzuki, Shuichi; Kozaki, Masatoshi; Okada, Keiji
Chemistry Letters, 2014 , vol. 43, # 5 p. 678 - 680
反应条件
1: 63 percent / Zn; NH4Cl / tetrahydrofuran; H2O / 3 h / 10 °C
2: 63 percent / methanol / 16 h / 20 °C
3: 73 percent / lead dioxide / methanol / 0.33 h / 20 °C
View Scheme
参考文献
Zhao, Ming; Li, Zheng; Peng, Li; Tang, Yu-Rong; Wang, Chao; Zhang, Ziding; Peng, Shiqi
Bioorganic and Medicinal Chemistry, 2007 , vol. 15, # 8 p. 2815 - 2826
反应条件
1: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid in dichloromethane
1 h; Ice cooling;
2: With sodium periodate in dichloromethane
Further stages.;
参考文献
Hirel, Catherine; Vostrikova, Kira E.; Pecaut, Jacques; Ovcharenko, Victor I.; Rey, Paul
Chemistry - A European Journal, 2001 , vol. 7, # 9 p. 2007 - 2014
反应条件
1.1: 92 percent / diethyl ether / ice cooling
2.1: m-chloroperbenzoic acid; NaHCO3 / CH2Cl2 / 1 h / Ice cooling
2.2: aq. NaIO4 / CH2Cl2
View Scheme
参考文献
Hirel, Catherine; Vostrikova, Kira E.; Pecaut, Jacques; Ovcharenko, Victor I.; Rey, Paul
Chemistry - A European Journal, 2001 , vol. 7, # 9 p. 2007 - 2014
反应条件
1: 63 percent / methanol / 16 h / 20 °C
2: 73 percent / lead dioxide / methanol / 0.33 h / 20 °C
View Scheme
参考文献
Zhao, Ming; Li, Zheng; Peng, Li; Tang, Yu-Rong; Wang, Chao; Zhang, Ziding; Peng, Shiqi
Bioorganic and Medicinal Chemistry, 2007 , vol. 15, # 8 p. 2815 - 2826
反应条件
1.1: dichloromethane / 0 °C / |Inert atmosphere
1.2: 0.17 h / 0 °C / |Inert atmosphere
2.1: tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran / |Inert atmosphere; |Reflux
View Scheme
参考文献
Tanimoto, Ryu; Suzuki, Shuichi; Kozaki, Masatoshi; Okada, Keiji
Chemistry Letters, 2014 , vol. 43, # 5 p. 678 - 680
反应条件
sodium periodate
Multistep reaction;
参考文献
Shimomura, Osamu; Abe, Kazuhisa; Hirota, Minoru
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1988 , p. 795 - 798
