2-(1,1-二甲基乙基)-4,5-二氢-4,4,5,5-四甲基-1H-咪唑-1-基氧基合成路线 (共 3 条)
反应条件
1: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid in dichloromethane
1 h; Ice cooling;
2: With sodium periodate in dichloromethane
Further stages.;
参考文献
Hirel, Catherine; Vostrikova, Kira E.; Pecaut, Jacques; Ovcharenko, Victor I.; Rey, Paul
Chemistry - A European Journal, 2001 , vol. 7, # 9 p. 2007 - 2014
反应条件
1.1: 95 percent / diethyl ether / ice cooling
2.1: m-chloroperbenzoic acid; NaHCO3 / CH2Cl2 / 1 h / Ice cooling
2.2: aq. NaIO4 / CH2Cl2
View Scheme
参考文献
Hirel, Catherine; Vostrikova, Kira E.; Pecaut, Jacques; Ovcharenko, Victor I.; Rey, Paul
Chemistry - A European Journal, 2001 , vol. 7, # 9 p. 2007 - 2014
反应条件
1.1: 81 percent / Sn; aq. HCl / 3 h / Heating
2.1: 95 percent / diethyl ether / ice cooling
3.1: m-chloroperbenzoic acid; NaHCO3 / CH2Cl2 / 1 h / Ice cooling
3.2: aq. NaIO4 / CH2Cl2
View Scheme
参考文献
Hirel, Catherine; Vostrikova, Kira E.; Pecaut, Jacques; Ovcharenko, Victor I.; Rey, Paul
Chemistry - A European Journal, 2001 , vol. 7, # 9 p. 2007 - 2014