1-叠氮基-3-甲氧基苯合成路线 （共 11 条）
反应条件
1: anhydrous HF / CH2Cl2; hexane / 1 h / 5 °C 2: 58 percent / Isoamylnitrite / tetrahydrofuran / 5 h / Heating View Scheme
参考文献
Journal of Organic Chemistry, , vol. 46, # 12 p. 2520 - 2528
反应条件
1: 1.) n-BuLi / 1.) THF, room temp., 16 h; 2.) THF, 15 deg C, 3.5 h 2: 89 percent / n-BuLi / tetrahydrofuran / 1.5 h / Ambient temperature View Scheme
参考文献
Nunno, L. Di; Scilimati, A.
Tetrahedron, 1986 , vol. 42, # 14 p. 3913 - 3920
反应条件
in hexane; dichloromethane; water
参考文献
Merck and Co., Inc.
Patent: US4145364 A1, 1979 ;
反应条件
hydrogen fluoride in hexane; dichloromethane T=5°C; 1 h; Yield given;
参考文献
Ng; Katzenellenbogen; Kilbourn
Journal of Organic Chemistry, 1981 , vol. 46, # 12 p. 2520 - 2528
反应条件
chloro-trimethyl-silane 1 h; Heating;
参考文献
Barua, Apurba; Bez, Ghanashyam; Barua, Nabin C.
Synlett, 1999 , # 5 p. 553 - 554
反应条件
tert.-butylnitrite; trimethylsilylazide in acetonitrile
T=0 - 20°C; 1 h;
参考文献
Mamidyala, Sreeman K.; Cooper, Matthew A.
Chemical Communications, 2013 , vol. 49, # 75 p. 8407 - 8409
反应条件
copper(l) iodide; sodium azide; sodium L-ascorbate; trans-N,N'-dimethylcyclohexane-1,2-diamine in ethanol
0.666667 h; Heating;
参考文献
Andersen, Jacob; Madsen, Ulf; Bjoerkling, Fredrik; Liang, Xifu
Synlett, 2005 , # 14 art. no. D17405ST, p. 2209 - 2213
反应条件
Cu(TMHD)2 in N,N-dimethyl-formamide
T=100°C; 6 h; Sealed tube;
参考文献
Lanke, Satish R.; Bhanage, Bhalchandra M.
Synthetic Communications, 2014 , vol. 44, # 3 p. 399 - 407
反应条件
copper(I) oxide; ammonium hydroxide; sodium azide; oxygen in water
T=25°C; 18 h;
参考文献
Yang, Haijun; Li, Yong; Jiang, Min; Wang, Junmei; Fu, Hua
Chemistry - A European Journal, 2011 , vol. 17, # 20 p. 5652 - 5660
反应条件
oxygen; nitrogen(II) oxide in tetrahydrofuran
3 h; Ambient temperature;
参考文献
Matsuya, Yuji; Itoh, Takashi; Nagata, Kazuhiro; Ohsawa, Akio
Tetrahedron, 1997 , vol. 53, # 46 p. 15701 - 15710
