氯(甲基二苯膦)金(I)合成路线 (共 12 条)
反应条件
in acetonitrile
byproducts: AgCl; stoich. amts.; addn. of AgClO4 and then PMePh2 to Au-complex; rapid filtration, crystn. on concn.; elem. anal.;
参考文献
McAuliffe, Charles A.; Parish, R. V. (Dick); Randall, P. David
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1979 , p. 1730 - 1735
反应条件
in ethanol
byproducts: AgCl; mixt. of tha Ag and Au compds. in ethanol, after removal of AgCl, was treated with PMePh2; ppt. redissolved in CH2Cl2, addn. of toluene, concn. gives 3 fraction, the first two are the bis-ligand complex, the third the 4-ligand complex, elem. anal.;
参考文献
Parish, R. V. ('Dick'); Parry, Owen; McAuliffe, Charles A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1981 , p. 2098 - 2104