苯甲酸-Alpha-13C合成路线 （共 27 条）
反应条件
1: 100 percent / LiAlH4 / tetrahydrofuran
2: 65 percent / PBr3 / diethyl ether / 20 h / Ambient temperature
View Scheme
参考文献
Hart, Lionel S.; Waddington, Catherine R.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1985 , p. 1607 - 1612
反应条件
1: 81 percent / diethyl ether / 2 h / 20 °C
2: 88 percent / t-BuOK / benzene / 16 h / 20 °C
3: 79 percent / CH3SO2N3; Et3N / H2O; acetonitrile / 2.5 h / 20 °C
4: dioxane; H2O / 0.75 h / Irradiation
View Scheme
参考文献
Haiss, Peter; Zeller, Klaus-Peter
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2003 , vol. 58, # 6 p. 595 - 605
反应条件
phosphorus pentachloride
T=60°C; 1.5 h;
参考文献
Seebach, Dieter; Haessig, Robert; Gabriel, Jozef
Helvetica Chimica Acta, 1983 , vol. 66, # 1 p. 308 - 337
反应条件
1: 97 percent / diethyl ether; methanol; H2O
2: 96 percent / LiAlH4 / diethyl ether / 2 h / Heating
3: 65 percent / SOCl2 / 2 h / Heating
View Scheme
参考文献
Sardella, D. J.; Mahathalang, P.; Mariani, H. A.; Boger, E.
Journal of Organic Chemistry, 1980 , vol. 45, # 11 p. 2064 - 2068
反应条件
1: 81 percent / diethyl ether / 2 h / 20 °C
2: 88 percent / t-BuOK / benzene / 16 h / 20 °C
3: 79 percent / CH3SO2N3; Et3N / H2O; acetonitrile / 2.5 h / 20 °C
4: dioxane; H2O / 0.75 h / Irradiation
View Scheme
参考文献
Haiss, Peter; Zeller, Klaus-Peter
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2003 , vol. 58, # 6 p. 595 - 605
反应条件
1: 99.9 percent / PCl5 / 1.5 h / 60 °C
2: 90 percent / diethyl ether / 1.) 0 deg C, 30 min; 2.) r.t., 2 h
View Scheme
参考文献
Seebach, Dieter; Haessig, Robert; Gabriel, Jozef
Helvetica Chimica Acta, 1983 , vol. 66, # 1 p. 308 - 337
反应条件
1: SOCl2
2: Na2O2
3: 1,2-dichloro-ethane / 840 h / 50 °C
View Scheme
参考文献
Takeuchi, Ken'ichi; Murai, Osamu; Matsui, Shin; Inoue, Takeshi; Kitagawa, Toshikazu; Okamoto, Kunio
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , # 9 p. 1301 - 1310
