2,6,10-三甲基十二烷合成路线 （共 28 条）
反应条件
hydrogen; Pd/α-Al2O3 T=160 - 200°C; P=1794.37 - 5931.67 Torr; Product distribution / selectivity;
参考文献
Naves,Y.-R.
Helvetica Chimica Acta, 1966 , vol. 49, p. 1029 - 1041
反应条件
platinum(IV) oxide; acetic acid Hydrogenation; farnesane;
参考文献
Fischer,F.G.
Justus Liebigs Annalen der Chemie, 1928 , vol. 464, p. 82,86
反应条件
(i) DMSO, (heating), (ii) H2, PtO2, AcOEt; Multistep reaction;
参考文献
Naves,Y.-R.
Helvetica Chimica Acta, 1966 , vol. 49, p. 1029 - 1041
反应条件
hydrogen; platinum(IV) oxide in ethanol
参考文献
McCarthy,E.D.; Calvin,M.
Tetrahedron, 1967 , vol. 23, p. 2609 - 2619
反应条件
hydrogen; palladium on activated charcoal T=26°C;
参考文献
Vander Meer; Williams; Lofgren
Tetrahedron Letters, 1981 , vol. 22, # 18 p. 1651 - 1654
反应条件
hydrogen; palladium T=140°C;
参考文献
Attygalle, Athula B.; Morgan, E. David
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1982 , p. 949 - 952
反应条件
1: 67.7 percent / methyl iodide, triphenyl phosphite / 20 h / Heating 2: 49.8 percent / benzene / 20 h / Heating 3: 1.) BuLi / 1.) ether, hexane, 30 min, 2.) ether, hexane, 1 h 4: H2 / 5percent Pd/C / ethanol View Scheme
参考文献
Suzuki, Takahisa
Agricultural and Biological Chemistry, 1981 , vol. 45, # 6 p. 1357 - 1364
反应条件
1: 49.8 percent / benzene / 20 h / Heating 2: 1.) BuLi / 1.) ether, hexane, 30 min, 2.) ether, hexane, 1 h 3: H2 / 5percent Pd/C / ethanol View Scheme
参考文献
Suzuki, Takahisa
Agricultural and Biological Chemistry, 1981 , vol. 45, # 6 p. 1357 - 1364
反应条件
hydrogen; palladium on activated charcoal in ethanol Yield given. Yields of byproduct given;
参考文献
Suzuki, Takahisa
Agricultural and Biological Chemistry, 1981 , vol. 45, # 6 p. 1357 - 1364
反应条件
Pt/Al2O3; lithium aluminium tetrahydride T=250°C; Hydrogenolysis; 0.666667 h;
参考文献
Aldrich, J. R.; Oliver, J. E.; Lusby, W. R.; Kochansky, J. P.; Borges, M.
Journal of Chemical Ecology, 1994 , vol. 20, # 5 p. 1103 - 1112
